Ethyl 8-nonenoate

Base Information

• Chemical Name: Ethyl 8-nonenoate
• CAS No.: 35194-39-9
• Molecular Formula: C11H20 O2
• Molecular Weight: 184.279
• Hs Code.: 2916190090
• DSSTox Substance ID: DTXSID30188688
• Nikkaji Number: J113.668B
• Wikidata: Q83060516
• Mol file: 35194-39-9.mol

Synonyms:ETHYL 8-NONENOATE;ethyl non-8-enoate;35194-39-9;8-Nonenoic acid, ethyl ester;MFCD00671847;Ethyl8-nonenoate;Ethyl 8-nonenoate #;8-Nonenoic acid ethyl ester;Non-8-enoic acid ethyl ester;SCHEMBL514850;DTXSID30188688;SOSSRQZGHXOQQE-UHFFFAOYSA-N;AKOS016016649

Chemical Property of Ethyl 8-nonenoate

Chemical Property:

• Vapor Pressure: 0.0647mmHg at 25°C
• Boiling Point: 230.8°C at 760 mmHg
• Flash Point: 90.6°C
• PSA: 26.30000
• Density: 0.883g/cm³
• LogP: 3.07610
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 184.146329876
• Heavy Atom Count: 13
• Complexity: 141

Purity/Quality:

99%, ^*data from raw suppliers

Ethyl8-nonenoate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)CCCCCCC=C

Technology Process of Ethyl 8-nonenoate

There total 11 articles about Ethyl 8-nonenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

ethanol (64-17-5) + non-8-enoic acid (31642-67-8) → ethyl non-8-enoate (35194-39-9)

Guidance literature:

With sulfuric acid; for 20h; Reflux;

DOI:10.1002/anie.201403537

Reference yield: 91.0%

(E)-Nona-2,8-dienoic acid ethyl ester (158627-60-2) → ethyl non-8-enoate (35194-39-9)

Guidance literature:

With sodium tetrahydroborate; copper(l) chloride; In tetrahydrofuran; methanol; at 0 ℃; for 6h; Inert atmosphere;

DOI:10.1002/ejoc.201001562

Reference yield: 86.0%

ethanol (64-17-5) + 1-Trimethylsiloxy-bicyclo[6.1.0]nonan (50338-49-3) → ethyl non-8-enoate (35194-39-9)

Guidance literature:

With trifluorormethanesulfonic acid; 1,1,3-trimethyl-3-phenylindan-4',5-dicarboxylic acid; for 0.0833333h; Ambient temperature;

DOI:10.1080/00397919808007168

upstream raw materials:

ethanol

non-8-enoyl chloride

non-8-enoic acid

9-chloro-nonanoic acid ethyl ester

Downstream raw materials:

non-8-en-1-ol

dimethyl (Z)-octadec-9-ene-1,18-dioate

Dimethyl (E)-octadec-9-enedioate

2-Benzenesulfinyl-1-{(4S,5R)-2-methyl-1,1-dioxo-4-[7-(tetrahydro-pyran-2-yloxy)-heptyl]-1λ⁶-isothiazolidin-5-yl}-octan-3-one

Refernces

• 1、 -. "PALLADIUM-CATALYZED DECARBONYLATION OF FATTY ACID ANHYDRIDES FOR THE PRODUCTION OF LINEAR ALPHA OLEFINS". Page/Page column. . Retrieved 2014/06/23.
• 2、 Ravu, Vengala Rao,Leung, Gulice Y. C.,Lim, Chek Shik,Ng, Sin Yee,Sum, Rong Ji,Chen, David Y.-K.. "Chemical synthesis and biological evaluation of second-generation palmerolide a analogues". supporting information; experimental part. p. 463 - 468. Retrieved 2011/04/17.