1-Chloroethyltrimethylsilane

Base Information

• Chemical Name: 1-Chloroethyltrimethylsilane
• CAS No.: 7787-87-3
• Molecular Formula: C5H13ClSi
• Molecular Weight: 136.697
• European Community (EC) Number: 232-135-8
• DSSTox Substance ID: DTXSID10884434
• Nikkaji Number: J268.693G
• Mol file: 7787-87-3.mol

Synonyms:1-Chloroethyltrimethylsilane;(1-Chloroethyl)trimethylsilane;7787-87-3;1-chloroethyl(trimethyl)silane;Silane, (1-chloroethyl)trimethyl-;.alpha.-Chloroethyltrimethylsilane;(1-chloro-ethyl)-trimethyl-silane;EINECS 232-135-8;1-chloroethyl-trimethylsilane;1-Chloroethyltrimethylsilane (tech.);alpha-Chloroethyltrimethylsilane;SCHEMBL1644232;(1-chloroethyl)-trimethylsilane;DTXSID10884434;MFCD00042611;AKOS006223199;CS-0455768;FT-0694115;S03975;(1-Chloroethyl)trimethylsilane technical, >=90% (GC);(1-Chloroethyl)trimethylsilane, technical, >=90% (GC)

Chemical Property of 1-Chloroethyltrimethylsilane

Chemical Property:

• Vapor Pressure: 21.4mmHg at 25°C
• Refractive Index: n20/D 1.422
• Boiling Point: 116.8 °C at 760 mmHg
• Flash Point: 11.7 °C
• PSA: 0.00000
• Density: 0.862 g/cm³
• LogP: 2.91100
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 136.0475046
• Heavy Atom Count: 7
• Complexity: 55.6

Purity/Quality:

99% ^*data from raw suppliers

(1-Chloroethyl)trimethylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: 11
• Safety Statements: 16-23-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metalloid Compounds (Silicon)
• Canonical SMILES: CC([Si](C)(C)C)Cl
• Uses: (1-Chloroethyl)trimethylsilane can be used as textile scouring agents.

Technology Process of 1-Chloroethyltrimethylsilane

There total 4 articles about 1-Chloroethyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

Trichloro-(1-chloro-ethyl)-silane (7787-82-8) → (1-chloroethyl)trimethylsilane (7787-87-3)

Guidance literature:

With CH₃MgBr; In not given;

DOI:10.1021/ja01214a004 DOI:10.1021/ja01207a037

Reference yield:

Chloromethyltrimethylsilane (2344-80-1) + methyl iodide (74-88-4) → (1-chloroethyl)trimethylsilane (7787-87-3)

Guidance literature:

With sec.-butyllithium; Multistep reaction;

DOI:10.1016/S0040-4039(00)99062-2

Reference yield:

Trichloro-(1-chloro-ethyl)-silane (7787-82-8) + methylmagnesium bromide (75-16-1) → (1-chloroethyl)trimethylsilane (7787-87-3)

Guidance literature:

With diethyl ether;

upstream raw materials:

diethyl ether

Trichloro-(1-chloro-ethyl)-silane

methylmagnesium bromide

Chloromethyltrimethylsilane

Downstream raw materials:

chloro-trimethyl-silane

isopropyldimethylsilyl chloride

12-<(phenylthio)ethyl>trimethylsilane

N-benzyl-N-<α-(trimethylsilyl)ethyl>amine

Refernces

• 1、 Winter, Nils,Trauner, Dirk. "Thiocarbonyl Ylide Chemistry Enables a Concise Synthesis of (±)-Hippolachnin A". supporting information. p. 11706 - 11709. Retrieved 2017/09/08.