Carbamodithioic acid, dibutyl-, sodium salt

Base Information

• Chemical Name: Carbamodithioic acid, dibutyl-, sodium salt
• CAS No.: 136-30-1
• Molecular Formula: C9H19NS2.Na
• Molecular Weight: 227.37
• Hs Code.: 2930909090
• Mol file: 136-30-1.mol

Synonyms:Carbamodithioic acid, dibutyl-, sodium salt;Sodium di-n-butyldithiocarbamate;SCHEMBL11567328

Chemical Property of Carbamodithioic acid, dibutyl-, sodium salt

Chemical Property:

• Appearance/Colour: Pale yellow green to light brown liquid
• Vapor Pressure: 0.0144mmHg at 25°C
• Melting Point: 123 - 125oC
• Boiling Point: 257.7 °C at 760 mmHg
• Flash Point: 109.6 °C
• PSA: 35.33000
• Density: 1,09 g/cm3
• LogP: 2.72040
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 228.08566124
• Heavy Atom Count: 13
• Complexity: 118

Purity/Quality:

99% ^*data from raw suppliers

Sodiumdibutylcarbamodithioate 40-50%inWater ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,C,N
• Hazard Codes: T,C,N
• Statements: 36/37/38-50-34-24-22
• Safety Statements: 26-36/37/39-61-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN(CCCC)C(=S)S.[Na]
• Uses: Sodium DBDT can be used for heavy metal wastewater treatment agent.

Technology Process of Carbamodithioic acid, dibutyl-, sodium salt

There total 1 articles about Carbamodithioic acid, dibutyl-, sodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.4%

carbon disulfide (75-15-0,12122-00-8) + dibutylamine (111-92-2) → sodium dibutyl dithiocarbamate (136-30-1)

Guidance literature:

With potassium hydroxide; In water; at 45 ℃; for 6h; Temperature; Cooling with ice; Autoclave; Large scale;

Reference yield: 88.0%

sodium dibutyl dithiocarbamate (136-30-1) → tetrabutylthiuram Disulfide (1634-02-2)

Guidance literature:

In water; at 25 ℃; Electrolysis; Flow reactor;

DOI:10.1039/d0gc03336g

Reference yield: 85.0%

uranyl nirate hexahydrate + sodium dibutyl dithiocarbamate (136-30-1) + Triphenylphosphine oxide (791-28-6) → bis(N,N-di(n-butyl)dithiocarbamato)dioxo(triphenylphosphine oxide)uranium(VI) (112614-55-8)

Guidance literature:

In methanol; dimethyl sulfoxide; byproducts: sodium nitrate; a soln. of 1 equiv of UO2(NO3)2*6H2O in MeOH-DMSO was treated with 1 equiv of Ph3PO and 2 equiv of n-Bu2NCS2Na, stirred for 30 min at room. temp.; filtered, pptd. by adding H2O to the filtrate, filtered by suction, washed with H2O, dried over CaCl2 under vac., purified by dissolving in MeOH-DMSO and reprecipitating with H2O; elem. anal.;

DOI:10.1016/S0020-1693(00)84474-6

upstream raw materials:

carbon disulfide

dibutylamine

Downstream raw materials:

chlorodiphenyl(N,N-dibutyldithiocarbamato)tellurium(IV)

diphenylbis(N,N-dibutyldithiocarbamato)tellurium(IV)

methylene bis-(di-n-butylamino-dithioformate)

C₂₁H₂₈BrNS₂Te

Refernces

• 1、 Ivanov,Zinkin,Gerasimenko,Sergienko. "Polynuclear complexes of gold(III) of the composition ([Au(S 2CNR2)2][AuCl4]) n (R = C4H9, R2 = (CH2)5): Synthesis, supramolecular structures, and thermal behavior". . p. 452 - 459. Retrieved 2011.
• 2、 Bai, Zhongjie,Zhang, Jinlong,Zhang, Qiuping,Zhang, Taofeng,Li, Jili,Zhao, Quanyi,Wang, Zhen,He, Dian,Cheng, Jie,Zhang, Jingke,Liu, Bin. "Synthesis, toxicities and bio-activities of manganese complexes with CO and H2S dual donors". . p. 339 - 356. Retrieved 2018.
• 3、 Ivanov,Loseva,Rodina,Gerasimenko,Novikova. "Gold(III)-iron(III) heteropolynuclear complexes ([Au{S2CNR2}2][FeCl4]) n (R = C4H9, iso-C4H9): Chemisorption synthesis, supramolecular self-organization, and thermal behavior". . p. 104 - 115. Retrieved 2016.
• 4、 -. "Easer and dithiocarbamate-containing mercaptopyrimidine derivative and preparation and application thereof". Paragraph 0038; 0039. . Retrieved 2019/10/01.
• 5、 Nasir, Jamal Abdul,Hafeez, Muhammad,Arshad, Muhammad,Ali, Naveed Zafar,Teixeira, Ivo F.,McPherson, Ian,Zia-ur-Rehman,Khan, M. Abdullah. "Photocatalytic Dehydrogenation of Formic Acid on CdS Nanorods through Ni and Co Redox Mediation under Mild Conditions". . p. 2587 - 2592. Retrieved 2018/07/31.