1-Naphthol,phosphate

Base Information

• Chemical Name: 1-Naphthol,phosphate
• CAS No.: 4004-51-7
• Molecular Formula: C30H21 O4 P
• Molecular Weight: 476.468
• Hs Code.: 2919900090
• Mol file: 4004-51-7.mol

Synonyms:1-Naphthalenol,phosphate (3:1) (9CI); 1-Naphthol, phosphate (3:1) (8CI); Phosphoric acidtri-1-naphthyl ester; Tri-1-naphthyl phosphate

Chemical Property of 1-Naphthol,phosphate

Chemical Property:

• PSA: 20.23000
• LogP: 3.62610

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Naphthol,phosphate

There total 8 articles about 1-Naphthol,phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium naphtholate (3019-88-3) → tri-1-naphthyl phosphate (4004-51-7)

Guidance literature:

With Amberlyst A-26 chloride; trichlorophosphate; In benzene; for 1.08333h; Ambient temperature;

DOI:10.1080/00397919408010211

Reference yield: 86.0%

α-naphthol (90-15-3) → tri-1-naphthyl phosphate (4004-51-7)

Guidance literature:

With sodium hydroxide; trichlorophosphate; for 2.5h; Microwave irradiation;

DOI:10.1080/00304940009355923

Reference yield:

tris(1-naphthyl) phosphite (13869-17-5) → tri-1-naphthyl phosphate (4004-51-7)

Guidance literature:

With Cumene hydroperoxide; In benzene; at 20 ℃; Rate constant;

upstream raw materials:

α-naphthol

sodium naphtholate

tris(1-naphthyl) phosphite

phosphorus pentachloride

Downstream raw materials:

1-(N-methyl-N-phenylamino)-naphthalene

N-(1-naphthyl)morpholine

α-naphthol

carbon dioxide

Refernces

• 1、 Huang, Jin-Hua,Yang, Lian-Ming. "Nickel-catalyzed amination of aryl phosphates through cleaving aryl C-O bonds". supporting information; experimental part. p. 3750 - 3753. Retrieved 2011/09/14.
• 2、 Nakamura, Mitsunobu,Okamoto, Yoshiki,Takamuku, Setsuo. "PHOTOCHEMICAL REACTIONS OF TRI-1-NAPHTHYL AND TRIS(8-QUINOLYL) PHOSPHATES". . p. 137 - 144. Retrieved 2007/10/03.