Ruthenium(3+)

Base Information

• Chemical Name: Ruthenium(3+)
• CAS No.: 22541-88-4
• Molecular Formula: Ru
• Molecular Weight: 101.07
• DSSTox Substance ID: DTXSID30177072
• Wikidata: Q27104732
• Mol file: 22541-88-4.mol

Synonyms:ruthenium(3+);Ruthenium, ion (Ru3+);22541-88-4;ruthenium(3+) ion;ruthenium(III) cation;CHEBI:49862;Ru(3+);DTXSID30177072;Q27104732

Chemical Property of Ruthenium(3+)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 101.904340
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Ru+3]

Technology Process of Ruthenium(3+)

There total 26 articles about Ruthenium(3+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium tetrahydroborate (16940-66-2) + ruthenium tetroxide (20427-56-9) → {RuO}(2+) (26317-68-0) + ruthenium(IV) oxide hydrate + ruthenium(III) (22541-88-4)

Guidance literature:

In sodium hydroxide; sulfuric acid; byproducts: BO2(1-), H2O, H2; alkaline B-compd. soln. addn. in excess to acidic RuO4 soln., pptn.;

Reference yield:

bis(η5-cyclopentadienyl)ruthenium (1287-13-4) → ruthenium(IV) + ruthenium(III) (22541-88-4)

Guidance literature:

With HNO₃;; In water; Electrochem. Process; anodic oxidation by aq. soln. of dil. HNO3 or stronger oxidants; first, Ru(C5H5)2(1+) is formed, which is distroyed to form Ru(3+) or Ru(4+);;

DOI:10.1021/ja01143a538

Reference yield:

ruthenium tetroxide (20427-56-9) → ruthenium(III) (22541-88-4)

Guidance literature:

With dihydrogen peroxide; In sulfuric acid; redn. to Ru(3+) with H2O2 in excess in H2SO4-soln.;;

DOI:10.1016/0022-1902(58)80042-1

upstream raw materials:

tris(2,2’-bipyridine)ruthenium(II)

pentaammineaquacobalt(III)

Fe(water)6⁽²⁺⁾

thallium(III) ion

Downstream raw materials:

ruthenium(II)

Refernces

• 1、 Tsai, Kelvin Yun-Da,Chang, I-Jy. "Oxidation of Bromide to Bromine by Ruthenium(II) Bipyridine-Type Complexes Using the Flash-Quench Technique". . p. 8497 - 8503. Retrieved 2017.
• 2、 Suvarna Latha,Adinarayana,Jayaprakash Rao. "Kinetics and mechanism of ruthenium (III) - Catalysed oxidation of pyrimidine bases by peroxydiphosphate in aqueous perchloric acid medium". . p. 1184 - 1187. Retrieved 2007/10/03.