potassium ethyl 4-oxidobenzoate

Base Information

• Chemical Name: potassium ethyl 4-oxidobenzoate
• CAS No.: 36457-19-9
• Molecular Formula: C9H9KO3
• Molecular Weight: 204.267
• Mol file: 36457-19-9.mol

Synonyms:Potassium ethyl 4-oxidobenzoate;potassium 4-ethoxycarbonylphenolate;EINECS 253-048-1;

Chemical Property of potassium ethyl 4-oxidobenzoate

Chemical Property:

• Vapor Pressure: 0.000759mmHg at 25°C
• Boiling Point: 297.5°Cat760mmHg
• Flash Point: 120.3°C
• PSA: 49.36000
• Density: g/cm³
• LogP: 2.00710

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of potassium ethyl 4-oxidobenzoate

There total 3 articles about potassium ethyl 4-oxidobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ethyl 4-hydroxybenzoate (120-47-8) + phenyl chloroformate (1885-14-9) → C9H9O3(1-)*K(1+) (36457-19-9) + ethyl phenyl carbonate (3878-46-4)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / diethyl ether

2: ethanol / 25 °C

With triethylamine; In diethyl ether; ethanol;

DOI:10.1246/bcsj.20120104

Reference yield:

phenyl 4-ethoxycarbonyl phenyl (1268380-09-1) + potassium ethoxide (917-58-8) → C9H9O3(1-)*K(1+) (36457-19-9) + ethyl phenyl carbonate (3878-46-4)

Guidance literature:

In ethanol; at 25 ℃; Concentration; Reagent/catalyst; Kinetics; Mechanism;

DOI:10.1246/bcsj.20120104

Reference yield:

potassium cyanide + 4-(ethoxycarbonyl)phenyl benzoate (7471-31-0) → benzoyl cyanide (613-90-1) + C9H9O3(1-)*K(1+) (36457-19-9)

Guidance literature:

In water; dimethyl sulfoxide; acetonitrile; at 25 ℃; Concentration; Kinetics; Mechanism;

DOI:10.5012/bkcs.2010.31.03.689

upstream raw materials:

4-(ethoxycarbonyl)phenyl benzoate

Ethyl 4-hydroxybenzoate

phenyl chloroformate

phenyl 4-ethoxycarbonyl phenyl

Refernces

• 1、 Kim, Song-I,Kim, Eun-Hee,Um, Ik-Hwan. "Kinetics and mechanism of nucleophilic displacement reactions of Y-substituted phenyl benzoates with cyanide Ion". experimental part. p. 689 - 693. Retrieved 2010/08/19.