4-phenylnaphthalen-1-ylboronic acid

Base Information

• Chemical Name: 4-phenylnaphthalen-1-ylboronic acid
• CAS No.: 372521-91-0
• Molecular Formula: C16H13BO2
• Molecular Weight: 248.089
• Mol file: 372521-91-0.mol

Synonyms:4-Phenyl(naphthalene-1-yl)boronic acid; 4-Phenylnaphthalene-1-boronic Acid

Chemical Property of 4-phenylnaphthalen-1-ylboronic acid

Chemical Property:

• Boiling Point: 449.4±48.0 °C(Predicted)
• PKA: 8.54±0.30(Predicted)
• PSA: 40.46000
• Density: 1.23
• LogP: 2.18660
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

(4-Phenylnaphthalen-1-yl)boronicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 41
• Safety Statements: 26-39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-phenylnaphthalen-1-ylboronic acid

There total 7 articles about 4-phenylnaphthalen-1-ylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

normal-butyllithium + 1-bromo-4-iodo-naphthanlene + boronic acid triisopropyl ester + 1-bromo-4-phenylnaphthalene (59951-65-4) + phenylboronic acid (98-80-6) → (4-phenylnaphthalene-1-yl)boronic acid (372521-91-0)

Guidance literature:

With sodium chloride; In hexane; toluene;

Reference yield: 80.0%

1-bromo-4-phenylnaphthalene (59951-65-4) → (4-phenylnaphthalene-1-yl)boronic acid (372521-91-0)

Guidance literature:

1-bromo-4-phenylnaphthalene; With n-butyllithium; In diethyl ether; hexane; toluene; at -40 - -5 ℃; for 1h;

With Triisopropyl borate; In diethyl ether; hexane; toluene; at 20 ℃; for 3.5h;

With hydrogenchloride; In diethyl ether; hexane; water; toluene;

Reference yield: 75.0%

→ (4-phenylnaphthalene-1-yl)boronic acid (372521-91-0)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

In tetrahydrofuran; at -78 - 20 ℃; for 3h;

upstream raw materials:

1-bromo-4-phenylnaphthalene

phenylboronic acid

1-phenylnaphthalene

diethyl ether

Downstream raw materials:

1-(4-bromo-2-nitrophenyl)-4-phenylnaphthalene

Refernces

• 1、 -. "Condensed-cyclic compound and organic light emitting device comprising the same". Paragraph 0361-0363. . Retrieved 2016/10/10.
• 2、 -. "ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME". Paragraph 105; 106; 107; 108. . Retrieved 2014/06/24.