Deuterium bromide

Base Information

• Chemical Name: Deuterium bromide
• CAS No.: 13536-59-9
• Molecular Formula: BrD
• Molecular Weight: 81.904
• Hs Code.: 2845901000
• European Community (EC) Number: 236-894-6
• DSSTox Substance ID: DTXSID501315998
• Nikkaji Number: J95.233H
• Wikipedia: Deuterium bromide
• Mol file: 13536-59-9.mol

Synonyms:Deuterium bromide;13536-59-9;Hydrobromic acid-d;(2H)bromane;EINECS 236-894-6;MFCD00044232;deutero-bromide;Br-D;D Br;Hydrogen bromide, deuterated;Deuterium bromide, 99 atom % D;DTXSID501315998;Deuterium bromide, 48% w/w in d2O;AKOS015904170;H0341;Deuterium bromide, 46 wt% in Deuterium oxide

Chemical Property of Deuterium bromide

Chemical Property:

• Appearance/Colour: clear colorless to slightly yellow solution
• Vapor Pressure: 334.7 psi ( 21 °C)
• Melting Point: - 87 °C(lit.)
• Boiling Point: 126 °C(lit.)
• Flash Point: 126°C
• PSA: 0.00000
• Density: 1.537 g/mL at 25 °C
• LogP: 0.95810
• Sensitive.: Moisture Sensitive
• Water Solubility.: soluble H2O [CRC10]
• XLogP3: 1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 80.93244
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99%, ^*data from raw suppliers

HydrobromicAcid-dSolution(48?wt.%inD2O) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C,T
• Statements: 23/24/25-34-35
• Safety Statements: 23-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Acids, Inorganic
• Canonical SMILES: Br
• Isomeric SMILES: [2H]Br
• Uses: NMR Solvent

Technology Process of Deuterium bromide

There total 11 articles about Deuterium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

boron tribromide (10294-33-4) + deuterium hydride → 31 (14720-24-2) + H(2)HBBr + hydrogen bromide (10035-10-6,12258-64-9) + deuterium bromide (13536-59-9) + dibromoborane (13709-65-4)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); react. of BBr3 with HD in an argon matrix (various conditions); monitored by IR in the argon matrix;

Reference yield:

water-d2 (7789-20-0) + phosphorus tribromide (7789-60-8) → deuterium bromide (13536-59-9)

Guidance literature:

DOI:10.1016/0301-0104(89)80208-3

Reference yield:

Bromotrichloromethane (75-62-7) + deuterium (16873-17-9,12184-84-8) → deuterium bromide (13536-59-9)

Guidance literature:

In neat (no solvent); Irradiation (UV/VIS); photolysis at 248-302°C; further products; mechanism discussed;;

upstream raw materials:

bromine

bromine

deuterium

water-d2

Downstream raw materials:

hydrogen chloride

hydrogen

deuterium

bromine

Refernces

• 1、 Xie, Jinchun,Zare, Richard N.. "Determination of absolute thermal rate costants for the charge-transfer reaction DBr+(2Πi,v+) + HBr -> HBr+(2Πi,v'+) + DBr". . p. 4293 - 4302. Retrieved 1992.
• 2、 Himmel, Hans-Joerg,Bahlo, Jan,Haussmann, Michael,Kurth, Fabian,Stoesser, Gregor,Schnoeckel, Hansgeorg. "Matrix reactivity of AlF and AlCl in the presence of HCl and HBr: Generation and characterization of the new Al(III) hydrides HAlFCl, HAlFBr, and HAlClBr and the monomeric mixed Al(III) halides AlX2Y (X, Y = F, Cl, or Br)". . p. 4952 - 4960. Retrieved 2008/10/08.
• 3、 Bedjanian, Yuri,Riffault, Véronique,Bras, Georges Le,Poulet, Gilles. "Kinetic study of the reactions of Br with HO2 and DO2". . p. 573 - 578. Retrieved 2007/10/03.