11-Fluoroundecanoic acid ethyl ester

Base Information

• Chemical Name: 11-Fluoroundecanoic acid ethyl ester
• CAS No.: 332-98-9
• Molecular Formula: C13H25FO2
• Molecular Weight: 232.3348
• Hs Code.: 2915900090
• Mol file: 332-98-9.mol

Synonyms:3,4-Ddu;Undecanoic acid,11-fluoro-,ethyl ester;Ethyl 11-fluorundecanoate;11-Fluor-undecansaeure-aethylester;11-Fluor-undecylsaeure-aethylester;11-fluoro-undecanoic acid ethyl ester;

Chemical Property of 11-Fluoroundecanoic acid ethyl ester

Chemical Property:

• Vapor Pressure: 0.00364mmHg at 25°C
• Boiling Point: 281.1°Cat760mmHg
• Flash Point: 120°C
• PSA: 26.30000
• Density: 0.921g/cm³
• LogP: 4.02990

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 11-Fluoroundecanoic acid ethyl ester

There total 3 articles about 11-Fluoroundecanoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

ethyl 11-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)undecanoate → ethyl 11-fluoroundecanoate (332-98-9)

Guidance literature:

With phosphoric acid; silver nitrate; Selectfluor; trifluoroacetic acid; In dichloromethane; water; at 50 ℃; for 8h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ja509548z

Reference yield:

11-bromoundecanoic acid ethyl ester (6271-23-4) → ethyl 11-fluoroundecanoate (332-98-9)

Guidance literature:

With potassium fluoride; ethylene glycol; at 130 ℃;

DOI:10.1021/jo01113a006

Reference yield:

1-chloro-10-fluorodecane (334-62-3) → ethyl 11-fluoroundecanoate (332-98-9)

Guidance literature:

With diethyl ether; n-Butyl chloride; magnesium; dann mit Chlorokohlensaeure-aethylester bei -75grad;

DOI:10.1021/jo01354a007

upstream raw materials:

1-chloro-10-fluorodecane

11-bromoundecanoic acid ethyl ester

Downstream raw materials:

11-fluoroundecanoic acid

12-fluorododecanoic acid

12-fluoro-dodecanenitrile

Refernces