Zinc diethanolate

Base Information

• Chemical Name: Zinc diethanolate
• CAS No.: 3851-22-7
• Molecular Formula: C2H6 O . 1/2 Zn
• Molecular Weight: 155.512
• European Community (EC) Number: 223-355-5
• DSSTox Substance ID: DTXSID60191842
• Nikkaji Number: J217.716A
• Mol file: 3851-22-7.mol

Synonyms:Zinc diethanolate;zinc;ethanolate;3851-22-7;EINECS 223-355-5;Diethoxyzinc;SCHEMBL489795;C2H6O.1/2Zn;C2-H6-O.1/2Zn;DTXSID60191842

Chemical Property of Zinc diethanolate

Chemical Property:

• Vapor Pressure: 82.8mmHg at 25°C
• Boiling Point: 72.6°Cat760mmHg
• Flash Point: 8.9°C
• PSA: 46.12000
• Density: g/cm³
• LogP: 0.87110
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 153.997221
• Heavy Atom Count: 7
• Complexity: 2.8

Purity/Quality:

99%, ^*data from raw suppliers

ZINC DIETHOXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 10-14
• Safety Statements: 16-43

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[O-].CC[O-].[Zn+2]

Technology Process of Zinc diethanolate

There total 3 articles about Zinc diethanolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

((C6F5)3Ge)3Hg(1-)*Tl(1+)*1.5CH3(OCH2)2CH3 = {((C6F5)3Ge)3Hg}Tl*1.5CH3(OCH2)2CH3 + zinc(II) iodide (10139-47-6) → thallium(I) iodide + bis[tris(pentafluorophenyl)germyl]mercury (35406-49-6) + tris(pentafuorophenyl)germane (42371-50-6) + zinc(II) ethanolate (3851-22-7)

Guidance literature:

With ethanol; In 1,2-dimethoxyethane; ethanol; at room temp.; anal. by IR, GLC and liq. chromy.;

DOI:10.1016/0022-328X(83)85045-1

Reference yield:

ethanol (64-17-5) + zinc (7440-66-6) → zinc(II) ethanolate (3851-22-7)

Guidance literature:

With tetrabutyl-ammonium chloride; In acetonitrile; Electrolysis; electrolysis of soln. of alc., tetrabutylammonium chloride in MeCN was conducted in H-type cell using Zn plate as anode and Pt foil as cathode; potential applied - 25 V, electricity passed - 700 Coulombs; solid sepd. in the anode was filtered; washed (MeCN, dry ether); dried (vac.); elem. anal.;

Reference yield:

→ zinc(II) ethanolate (3851-22-7)

Guidance literature:

langsame Autoxidation v. Diethylzink in Anisol (6 Wochen);

DOI:10.1039/jr9600004130

upstream raw materials:

ethanol

zinc

zinc(II) iodide

Refernces

• 1、 Razuvaev, G. A.,Bochkarev, M. N.,Pankratov, L. V.. "REACTIVITY OF THALLIUM TRIS MERCURATE". . p. 135 - 144. Retrieved 2007/10/02.