Octadecylamine hydrochloride

Base Information

• Chemical Name: Octadecylamine hydrochloride
• CAS No.: 1838-08-0
• Molecular Formula: C18H39 N . Cl H
• Molecular Weight: 305.975
• Hs Code.: 2921199090
• European Community (EC) Number: 217-410-2
• UNII: 3V3V50Q0SJ
• DSSTox Substance ID: DTXSID00883759
• Wikidata: Q27258068
• ChEMBL ID: CHEMBL331817
• Mol file: 1838-08-0.mol

Synonyms:1-octadecanamine, hydrochloride;1-octadecanamine, hydrochloride (1:1);1-octadecylamine;octadecyl ammonium chloride;octadecylamine;octadecylamine hydrochloride;stearamine;stearyl amine;stearylamine;stearylamine hydrochloride;stearylammonium chloride

Chemical Property of Octadecylamine hydrochloride

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: 157-160 °C
• Boiling Point: 348.9 °C at 760 mmHg
• Flash Point: 154.1 °C
• PSA: 26.02000
• LogP: 7.70890
• Solubility.: Soluble in hot methanol.
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 16
• Exact Mass: 305.2849280
• Heavy Atom Count: 20
• Complexity: 145

Purity/Quality:

98%,99%, ^*data from raw suppliers

Octadecylamine Hydrochloride ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCCCCCN.Cl
• Uses: 1-Octadecylamine hydrochloride is used as organic intermediates.

Technology Process of Octadecylamine hydrochloride

There total 4 articles about Octadecylamine hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

stearamide (124-26-5) → octadecylamine hydrochloride (1838-08-0)

Guidance literature:

stearamide; With titanium(IV) isopropylate; In toluene; at 20 - 100 ℃;

With hydrogenchloride; In diethyl ether; toluene;

DOI:10.1016/j.tetlet.2011.05.109

Reference yield:

1-aminooctadecane (124-30-1) → octadecylamine hydrochloride (1838-08-0)

Guidance literature:

With hydrogenchloride; In water; butan-1-ol; at 60 ℃;

Reference yield:

stearonitrile (638-65-3) → octadecylamine hydrochloride (1838-08-0)

Guidance literature:

stearonitrile; With [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); {[(phenylphosphinediyl)bis(2,1-phenylene)]bis(methylene)}bis(di-tert-butylphosphine); hydrogen; In isopropyl alcohol; at 50 ℃; for 17h; under 11251.1 Torr; Inert atmosphere; Autoclave;

With hydrogenchloride; In methanol; water; at 20 ℃; for 0.5h;

DOI:10.1002/cctc.201501367

upstream raw materials:

stearamide

1-aminooctadecane

stearonitrile

Downstream raw materials:

octadecyl isocyanate

1-formamidooctadecane

1-(4-dodecyloxyphenyl)-3-octadecylamino-2-propen-1-one

octadecylurea

Refernces

• 1、 Adam, Rosa,Bheeter, Charles Beromeo,Jackstell, Ralf,Beller, Matthias. "A Mild and Base-Free Protocol for the Ruthenium-Catalyzed Hydrogenation of Aliphatic and Aromatic Nitriles with Tridentate Phosphine Ligands". . p. 1329 - 1334. Retrieved 2016/04/20.
• 2、 Sanz, Dionisia,Claramunt, Rosa M.,García, M. ángeles,Alkorta, Ibon,Elguero, José. "A 13C and 15N experimental NMR and theoretical study of the structure of linear primary aliphatic amines and ammonium salts: From C1 to C18". experimental part. p. 4633 - 4639. Retrieved 2011/07/09.