Glycerol 1,3-Dimethacrylate

Base Information

• Chemical Name: Glycerol 1,3-Dimethacrylate
• CAS No.: 1830-78-0
• Deprecated CAS: 141681-57-4,1610385-27-7,181224-53-3,2714521-57-8
• Molecular Formula: C11H16 O5
• Molecular Weight: 228.245
• Hs Code.: 29161400
• European Community (EC) Number: 931-227-1,217-388-4,608-218-3
• UNII: 6VNY892Q3Y
• DSSTox Substance ID: DTXSID5062009
• Nikkaji Number: J25.509B
• Wikidata: Q27265595
• Mol file: 1830-78-0.mol

Synonyms:Glycerol 1,3-Dimethacrylate;1830-78-0;Bis(methacryloyloxy)propanol;2-Hydroxy-1,3-propanediyl bismethacrylate;2-hydroxypropane-1,3-diyl bis(2-methylacrylate);[2-hydroxy-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate;Glyceryl 1,3-dimethacrylate;UNII-6VNY892Q3Y;6VNY892Q3Y;EINECS 217-388-4;1,2,3-Propanetriol, 1,3-di(2-methyl-2-propenoate);Glycerol 1,3-dimethacrylate check CAS;2-Propenoic acid, 2-methyl-, 2-hydroxy-1,3-propanediyl ester;2-hydroxy-3-[(2-methylprop-2-enoyl)oxy]propyl 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-, 1,1'-(2-hydroxy-1,3-propanediyl) ester;28497-59-8;glycerol-1,3-dimethacrylate;SCHEMBL94906;DTXSID5062009;GLYCERIN 1,3-DIMETHACRYLATE;MFCD00066299;2-OH-1,3-propanediyl bismethacrylate;AKOS015903275;BS-42398;HYDROXY-1,3-DIMETHACRYLOYLOXYPROPANE;B2938;CS-0328464;METHACRYLIC ACID, 2-HYDROXYTRIMETHYLENE ESTER;W-109716;Q27265595;2-PROPENOIC ACID, 2-METHYL-, 1,1'-(2-HYDROXY-1,3- PROPANEDIYL) ESTER;103135-96-2

Chemical Property of Glycerol 1,3-Dimethacrylate

Chemical Property:

• Vapor Pressure: 3.28E-05mmHg at 25°C
• Melting Point: -33°C
• Refractive Index: n20/D 1.472(lit.)
• Boiling Point: 120 °C1 mm Hg(lit.)
• PKA: 12.49±0.20(Predicted)
• Flash Point: 114.6°C
• PSA: 72.83000
• Density: 1.114g/cm³
• LogP: 0.58590
• Storage Temp.: 2-8°C
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 8
• Exact Mass: 228.09977361
• Heavy Atom Count: 16
• Complexity: 276

Purity/Quality:

GlycerolDimethacrylate(Mixtureof1,2-And1,3-Form) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC(COC(=O)C(=C)C)O

Technology Process of Glycerol 1,3-Dimethacrylate

There total 6 articles about Glycerol 1,3-Dimethacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → glyceryl tri(methyl)acrylate (7401-88-9) + 2,3-dihydroxypropyl methacrylate (5919-74-4) + glycerol-1,3-dimethacrylate (1830-78-0)

Guidance literature:

With toluene-4-sulfonic acid; p-benzoquinone; at 90 ℃;

Reference yield:

methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → glycerine dimethacrylate (101525-90-0) + 2,3-dihydroxypropyl methacrylate (5919-74-4) + glycerol-1,3-dimethacrylate (1830-78-0) + 2-hydroxy-1-(hydroxymethyl)ethyl methacrylate

Guidance literature:

With Novozyme 435; In tert-Amyl alcohol; at 50 ℃; for 120h; Inert atmosphere; Molecular sieve; Enzymatic reaction;

DOI:10.1016/j.molcatb.2009.09.008

Reference yield:

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → glycerol-1,3-dimethacrylate (1830-78-0)

Guidance literature:

With sulfuric acid; In toluene; at 20 ℃; Reflux;

upstream raw materials:

methacrylic acid methyl ester

glycerol

poly(methacrylic acid)

2,3-Epoxypropyl methacrylate

Downstream raw materials:

glyceryl tri(methyl)acrylate

1,3 glycerol dimethacrylate phosphate

Refernces

• 1、 -. "MANUFACTURING METHOD OF ESTER COMPOUND". Paragraph 0028-0031. . Retrieved 2016/02/18.
• 2、 Popescu, Dragos,Hoogenboom, Richard,Keul, Helmut,Moeller, Martin. "Hydroxy functional acrylate and methacrylate monomers prepared via lipase-catalyzed transacylation reactions". experimental part. p. 80 - 89. Retrieved 2010/08/20.