Glyceryl methacrylate

Base Information

• Chemical Name: Glyceryl methacrylate
• CAS No.: 5919-74-4
• Deprecated CAS: 201594-54-9,205515-17-9,96614-21-0,313344-18-2,338445-53-7,543689-70-9,1174669-93-2,1329498-79-4,1558026-26-8,1329498-79-4,205515-17-9,313344-18-2,338445-53-7,543689-70-9,96614-21-0
• Molecular Formula: C7H12O4
• Molecular Weight: 160.17
• Hs Code.: 2916140000
• European Community (EC) Number: 227-642-6
• UNII: REQ9YDH79C
• DSSTox Substance ID: DTXSID7057781
• Nikkaji Number: J81.999I
• ChEMBL ID: CHEMBL3561352
• Mol file: 5919-74-4.mol

Synonyms:glyceryl methacrylate;glyceryl monomethacrylate

Chemical Property of Glyceryl methacrylate

Chemical Property:

• Vapor Pressure: 5.43E-05mmHg at 25°C
• Melting Point: 140℃/0.6mm
• Refractive Index: 1.475
• Boiling Point: 310.3 °C at 760 mmHg
• PKA: 13.09±0.20(Predicted)
• Flash Point: 127.3 °C
• PSA: 66.76000
• Density: 1.161 g/cm³
• LogP: -0.54110
• Storage Temp.: 2-8°C(protect from light)
• Water Solubility.: 100g/L at 25℃
• XLogP3: -0.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 160.07355886
• Heavy Atom Count: 11
• Complexity: 153

Purity/Quality:

99.9% ^*data from raw suppliers

Glyceryl monomethacrylate 96% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC(CO)O

Technology Process of Glyceryl methacrylate

There total 10 articles about Glyceryl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

→ 2,3-dihydroxypropyl methacrylate (5919-74-4)

Guidance literature:

With 2,6-di-tert-butyl-4-methyl-phenol; water; at 60 ℃; for 3h; Reagent/catalyst;

Reference yield: 93.2%

2,3-Epoxypropyl methacrylate (106-91-2,25067-05-4,98104-93-9) → 2,3-dihydroxypropyl methacrylate (5919-74-4)

Guidance literature:

With Cs_2.5H_0.5PMo₁₂O₄₀; water; In tetrahydrofuran; at 35 - 70 ℃; for 4h; Reagent/catalyst;

Reference yield: 80.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → 2,3-dihydroxypropyl methacrylate (5919-74-4)

Guidance literature:

With sulfuric acid; In water; at 70 ℃; for 6h;

upstream raw materials:

2,3-Epoxypropyl methacrylate

2-methyl-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

Methacryloyl chloride

Downstream raw materials:

(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate

2-styryl-4-methacryloyloxymethyl-1,3-dioxolane

Refernces

• 1、 Hild. "". . p. 1947,1952. Retrieved 1976.
• 2、 Nalawade, Archana C.,Ghorpade, Ravindra V.,Shadbar, Sadiqua,Qureshi, Mohammed Shadbar,Chavan,Khan, Ayesha A.,Ponrathnam. "Inverse high internal phase emulsion polymerization (i-HIPE) of GMMA, HEMA and GDMA for the preparation of superporous hydrogels as a tissue engineering scaffold". . p. 450 - 460. Retrieved 2016.
• 3、 Natongchai, Wuttichai,Posada-Pérez, Sergio,Phungpanya, Chalida,Luque-Urrutia, Jesús Antonio,Solà, Miquel,D'Elia, Valerio,Poater, Albert. "Enhancing the Catalytic Performance of Group I, II Metal Halides in the Cycloaddition of CO2to Epoxides under Atmospheric Conditions by Cooperation with Homogeneous and Heterogeneous Highly Nucleophilic Aminopyridines: Experimental and Theoretical Study". . p. 2873 - 2886. Retrieved 2022/02/10.
• 4、 -. "METHOD FOR PRODUCING GLYCEROL MONO(METH)ACRYLATE". Page/Page column 6-8. . Retrieved 2021/01/22.