CID 9796654

Base Information

• Chemical Name: CID 9796654
• CAS No.: 1983-10-4
• Molecular Formula: C12H27FSn
• Molecular Weight: 309.055
• Hs Code.: 2931900090
• Mol file: 1983-10-4.mol

Synonyms:SCHEMBL394141;AKOS015833240;T0678

Chemical Property of CID 9796654

Chemical Property:

• Vapor Pressure: 0.0135mmHg at 25°C
• Melting Point: 269-271 °C(lit.)
• Boiling Point: 267.3 °C at 760mmHg
• Flash Point: >150 °C
• PSA: 0.00000
• Density: 1.28 g/cm³
• LogP: 5.30170
• Sensitive.: Moisture Sensitive
• Water Solubility.: Soluble in nonpolar organic solvents. Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 310.111882
• Heavy Atom Count: 14
• Complexity: 72.1

Purity/Quality:

99%, ^*data from raw suppliers

Tri-n-butyltin fluoride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 35-36/37/39-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn+](CCCC)CCCC.[F-]
• Uses: Tri-n-butyltin fluoride is a reagent used for the selective desilylation of bis(silyl) enol ethers. It is also used as antifoulant for marine paints; reagent.

Technology Process of CID 9796654

There total 25 articles about CID 9796654 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pivaloyl fluoride (1478-62-2) + tributyltin methoxide (1067-52-3) → tributyltin fluoride (1983-10-4,27615-98-1)

Guidance literature:

0°C; <1 min;

DOI:10.1016/S0022-328X(00)82592-9

Reference yield: 91.0%

(pentamethylcyclopentadienyl)titanium fluoride + bis(tri-n-butyltin)oxide (56-35-9) → (C5(CH3)5TiF(O))4 + tributyltin fluoride (1983-10-4,27615-98-1)

Guidance literature:

In toluene; dropping O(SnBu3)2 in toluene to (C5Me5)TiF3 in toluene under stirring; removal of FSnBu3 by filtration after 12 h, removal of the solvent from the filtrate in vacuo and recrystn. of the residue from n-hexane, elem. anal.;

Reference yield: 87.0%

tributylphenylstannane (960-16-7) + cesium fluoride (13400-13-0) → tributyltin fluoride (1983-10-4,27615-98-1)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; bromobenzene; lithium chloride; In N,N-dimethyl-formamide; at 110 ℃; for 12h; Reagent/catalyst; Inert atmosphere;

upstream raw materials:

1,3,5-Trioxan

Tributyl-((E)-4-phenyl-but-2-enyl)-stannane

(E)-1-tri-n-butylstannyl-2-undecene

1-bromo-hexane

Downstream raw materials:

tributyltin chloride

tributylphenylstannane

(E)-tributyl(1,2-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)vinyl)stannane

(Z)-tributyl(1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)vinyl)stannane

Refernces

• 1、 Licht et al.. "". . p. 271,273,275. Retrieved 1971.
• 2、 Christy, R. W.. "". . p. 1884 - 1888. Retrieved 1962.
• 3、 -. "Organic tin compound cycle application Stille method of synthesis of biphenyl". Paragraph 0051; 0053-0054. . Retrieved 2017/05/12.
• 4、 Ballivet-Tkatchenko,Douteau,Stutzmann. "Reactivity of carbon dioxide with n-butyl(phenoxy)-,(alkoxy)-, and (oxo)stannanes: insight into dimethyl carbonate synthesis". . p. 4563 - 4567. Retrieved 2008/10/08.