p-Bis(hydroperoxyisopropyl)benzene

Base Information

• Chemical Name: p-Bis(hydroperoxyisopropyl)benzene
• CAS No.: 3159-98-6
• Molecular Formula: C12H18 O4
• Molecular Weight: 226.273
• European Community (EC) Number: 608-649-7,922-776-8
• DSSTox Substance ID: DTXSID10185478
• Nikkaji Number: J472.943I
• Wikidata: Q83056507
• Mol file: 3159-98-6.mol

Synonyms:Percumyl P;p-Bis(hydroperoxyisopropyl)benzene;1,4-bis(2-hydroperoxypropan-2-yl)benzene;3159-98-6;p-Diisopropylbenzene dihydroperoxide;BRN 2052060;(p-Phenylenediisopropylidene)dihydroperoxide;Hydroperoxide, (1,4-phenylenebis(1-methylethylidene))bis-;(1,4-Phenylenebis(1-methylethylidene))bishydroperoxide;Hydroperoxide, (p-phenylenediisopropylidene)di-;4-06-00-06056 (Beilstein Handbook Reference);SCHEMBL5943678;DTXSID10185478;LS-77275;1,4-bis-(1-hydroperoxy-1-methylethyl)-benzene

Chemical Property of p-Bis(hydroperoxyisopropyl)benzene

Chemical Property:

• Vapor Pressure: 3.16E-07mmHg at 25°C
• Boiling Point: 403.2°Cat760mmHg
• Flash Point: 197.7°C
• PSA: 58.92000
• Density: 1.145g/cm³
• LogP: 3.13600
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 226.12050905
• Heavy Atom Count: 16
• Complexity: 193

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C1=CC=C(C=C1)C(C)(C)OO)OO

Technology Process of p-Bis(hydroperoxyisopropyl)benzene

There total 5 articles about p-Bis(hydroperoxyisopropyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

α,α,α',α'-tetramethyl-1,4-benzenedimethanol (2948-46-1) → p-diisopropylbenzene dihydroperoxide (3159-98-6)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; In toluene; at 50 ℃; for 5h;

DOI:10.1007/s007060170069

Reference yield:

1,4-bis(1-methylethyl)benzene (100-18-5) → 1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide (98-49-7,30498-45-4) + p-diisopropylbenzene dihydroperoxide (3159-98-6)

Guidance literature:

With calcium hydroxide; air; manganese(II); at 112 ℃;

Reference yield:

1,4-bis(1-methylethyl)benzene (100-18-5) → 1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide (98-49-7,30498-45-4) + p-diisopropylbenzene dihydroperoxide (3159-98-6)

Guidance literature:

at 85 ℃; Kinetics;

DOI:10.1080/0269249X.2000.9705501

upstream raw materials:

1,4-bis(1-methylethyl)benzene

α,α,α',α'-tetramethyl-1,4-benzenedimethanol

Downstream raw materials:

α,α,α',α'-tetramethyl-1,4-benzenedimethanol

hydroquinone

α,α-dimethyl-p-isopropylbenzyl alcohol

1-(4-isopropyl-phenyl)-1-methyl-ethyl hydroperoxide

Refernces

• 1、 Tsyskovskaya, I. V.,Potekhin, V. M.. "CATALYTIC DECOMPOSITION OF p-DIISOPROPYLBENZENE DIHYDROPEROXIDE". . p. 1262 - 1265. Retrieved 2007/10/02.