Trimethylsilyl methacrylate

Base Information

• Chemical Name: Trimethylsilyl methacrylate
• CAS No.: 13688-56-7
• Molecular Formula: C7H14O2Si
• Molecular Weight: 158.272
• Hs Code.: 29319090
• European Community (EC) Number: 629-466-9
• DSSTox Substance ID: DTXSID5074002
• Nikkaji Number: J266.767C
• Wikidata: Q72514499
• Mol file: 13688-56-7.mol

Synonyms:Trimethylsilyl methacrylate;13688-56-7;trimethylsilyl 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-, trimethylsilyl ester;methacryloxytrimethylsilane;trimethylsilylmethacrylate;Methacrylic acid, TMS derivative;Methacrylic Acid Trimethylsilyl Ester;(Trimethylsilyl)methacrylate;Trimethylsilyl 2-methylpropenoate;SCHEMBL139709;DTXSID5074002;(Trimethylsilyl)methacrylate, 98%;MFCD00053868;AKOS025294422;GS-5747;FT-0694052;T3293;T3580;H10534;J-006933;Trimethylsilyl Methacrylate, 98%, Stabilized With Bht;Trimethylsilyl Methacrylate (stabilized with N-Nitrosodiisopropanolamine);25499-03-0

Chemical Property of Trimethylsilyl methacrylate

Chemical Property:

• Appearance/Colour: clear slightly yellow liquid
• Vapor Pressure: <5 mm Hg ( 25 °C)
• Refractive Index: n20/D 1.415(lit.)
• Boiling Point: 146.824 °C at 760 mmHg
• Flash Point: 30.079 °C
• PSA: 26.30000
• Density: 0.888 g/cm³
• LogP: 1.94060
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 158.076306220
• Heavy Atom Count: 10
• Complexity: 156

Purity/Quality:

98%,99%, ^*data from raw suppliers

TrimethylsilylMethacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 10-36/37/38-42/43
• Safety Statements: 22-26-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C(=O)O[Si](C)(C)C

Technology Process of Trimethylsilyl methacrylate

There total 9 articles about Trimethylsilyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.1%

methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → trimethylsilyl methacrylate (13688-56-7)

Guidance literature:

With tris(pentafluorophenyl)borate; 4-methoxy-phenol; In tetrahydrofuran; for 0.75h; Green chemistry;

Reference yield: 80.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + N,N'-bis(trimethylsilyl)urea (18297-63-7,127290-39-5) → trimethylsilyl methacrylate (13688-56-7)

Guidance literature:

In dichloromethane; at 40 ℃; for 2h;

DOI:10.1055/s-1981-29605

Reference yield: 56.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + Hexamethyldisiloxane (107-46-0) → trimethylsilyl methacrylate (13688-56-7)

Guidance literature:

With ammonium sulfate; at 120 ℃;

DOI:10.1016/S0040-4039(01)93289-7

upstream raw materials:

chloro-trimethyl-silane

poly(methacrylic acid)

sodium methacrylate

3-(trimethylsilyl)-2-oxazolidinone

Downstream raw materials:

Hexamethyldisiloxane

2-methylacrylic acid trityl ester

methacrylic acid bromide

chloro-trimethyl-silane

Refernces

• 1、 -. "Method for preparing silicone acrylate by using Piers-Rubinsztajn reaction". Paragraph 0041-0042. . Retrieved 2020/01/03.
• 2、 -. "Process for the preparation of trialkylsilylated carboxylate monomers, the obtained trialkylsilylated carboxylate monomers and their use in antifouling coatings". . . Retrieved 2008/06/13.