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CAS No.: | 13688-56-7 |
---|---|
Name: | TRIMETHYLSILYL METHACRYLATE |
Article Data: | 15 |
Molecular Structure: | |
Formula: | C7H14O2Si |
Molecular Weight: | 158.272 |
Synonyms: | Methacrylic acid,trimethylsilyl ester (7CI,8CI);Silanol, trimethyl-, methacrylate (6CI);T3633;Trimethylsilyl 2-methylacrylate; |
Density: | 0.888 g/cm3 |
Boiling Point: | 146.824 °C at 760 mmHg |
Flash Point: | 30.079 °C |
Appearance: | clear slightly yellow liquid |
Hazard Symbols: | Xn |
Risk Codes: | 10-36/37/38-42/43 |
Safety: | 22-26-36/37 |
PSA: | 26.30000 |
LogP: | 1.94060 |
methacrylic acid methyl ester
trimethylsilyl methacrylate
Conditions | Yield |
---|---|
With tris(pentafluorophenyl)borate; 4-methoxy-phenol In tetrahydrofuran for 0.75h; Green chemistry; | 90.1% |
poly(methacrylic acid)
N,N'-bis(trimethylsilyl)urea
trimethylsilyl methacrylate
Conditions | Yield |
---|---|
In dichloromethane at 40℃; for 2h; | 80% |
Conditions | Yield |
---|---|
With ammonium sulfate at 120℃; | 56% |
Conditions | Yield |
---|---|
With N,N-diethylaniline | |
With 1-methyl-1H-imidazole at 45 - 90℃; for 3.75h; Product distribution / selectivity; Inert atmosphere; Industry scale; | 99 %Chromat. |
Conditions | Yield |
---|---|
With hydroquinone In benzene |
3-(trimethylsilyl)-2-oxazolidinone
poly(methacrylic acid)
trimethylsilyl methacrylate
Conditions | Yield |
---|---|
With triethylamine In dichloromethane for 0.5h; Ambient temperature; |
poly(methacrylic acid)
1,1,1,3,3,3-hexamethyl-disilazane
trimethylsilyl methacrylate
Conditions | Yield |
---|---|
With hydroquinone for 3h; Heating; |
Conditions | Yield |
---|---|
In hexane |
trityl fluoride
trimethylsilyl methacrylate
A
trimethylsilyl fluoride
B
2-methylacrylic acid trityl ester
Conditions | Yield |
---|---|
With silicon tetrafluoride In acetonitrile at 14℃; for 6h; | A n/a B 94% |
trimethylsilan
trimethylsilyl methacrylate
1,1-bis(trimethylsiloxy)-2-methylprop-1-ene
Conditions | Yield |
---|---|
With 2,6-di-tert-butyl-4-methyl-phenol; rhodium(III) chloride In tetrahydrofuran at 40 - 50℃; | 78% |
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The 2-Propenoic acid,2-methyl-, trimethylsilyl ester is an organic compound with the formula C7H14O2Si. The IUPAC name of this chemical is trimethylsilyl 2-methylprop-2-enoate. With the CAS registry number 13688-56-7, it is also named as Trimethylsilyl-2-methylacrylat.
Physical properties about 2-Propenoic acid,2-methyl-, trimethylsilyl ester are: (1)ACD/LogP: 2.39; (2)ACD/LogD (pH 5.5): 2.39; (3)ACD/LogD (pH 7.4): 2.39; (4)ACD/BCF (pH 5.5): 38.32; (5)ACD/BCF (pH 7.4): 38.32; (6)ACD/KOC (pH 5.5): 473.14; (7)ACD/KOC (pH 7.4): 473.14; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 3; (10)Polar Surface Area: 26.3 Å2; (11)Index of Refraction: 1.414; (12)Molar Refractivity: 44.53 cm3; (13)Molar Volume: 178.1 cm3; (14)Polarizability: 17.65×10-24cm3; (15)Surface Tension: 20.6 dyne/cm; (16)Density: 0.888 g/cm3; (17)Flash Point: 30.1 °C; (18)Enthalpy of Vaporization: 38.38 kJ/mol; (19)Boiling Point: 146.8 °C at 760 mmHg; (20)Vapour Pressure: 4.55 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES: O=C(O[Si](C)(C)C)\C(=C)C
(2)InChI: InChI=1/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3
(3)InChIKey: PGQNYIRJCLTTOJ-UHFFFAOYAV
(4)Std. InChI: InChI=1S/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3
(5)Std. InChIKey: PGQNYIRJCLTTOJ-UHFFFAOYSA-N