(THF)3-phenylethynylpraseodymium(III) iodide

Base Information

• Chemical Name: (THF)3-phenylethynylpraseodymium(III) iodide
• CAS No.: 1373445-38-5
• Molecular Formula: C₂₀H₂₉I₂O₃Pr
• Molecular Weight: 712.165
• Mol file: 1373445-38-5.mol

Synonyms:(THF)3-phenylethynylpraseodymium(III) iodide

Chemical Property of (THF)3-phenylethynylpraseodymium(III) iodide

Chemical Property:

Purity/Quality:

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Technology Process of (THF)3-phenylethynylpraseodymium(III) iodide

There total 1 articles about (THF)3-phenylethynylpraseodymium(III) iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

trimethylsilyl iodide (16029-98-4) + hexa(tetrahydrofuranate)dipraseodymium tris(triphenylethynylcuprate) → copper(I) phenylacetylide (13146-23-1) + (THF)3-phenylethynylpraseodymium(III) iodide (1373445-38-5) + phenylacetylene (536-74-3)

Guidance literature:

With Me₃SiCCPh; In tetrahydrofuran; using Schlenk techniques; Me3SiI added to soln. of Pr complex (molar ratio 6:1) in THF; kept at room temp. for 10 d; PhC2Cu ppt. sepd.; solvent distd. off from filtrate, hexane added, residue washed with hexane, dried in vac. (PhC2PrI2(THF)3); elem. anal.;

DOI:10.1134/S1070363212030231

upstream raw materials:

trimethylsilyl iodide

Refernces