7H-Dibenzo[c,g]carbazole

Base Information

• Chemical Name: 7H-Dibenzo[c,g]carbazole
• CAS No.: 194-59-2
• Molecular Formula: C20H13 N
• Molecular Weight: 267.33
• Hs Code.: 2933990090
• European Community (EC) Number: 205-895-3
• NSC Number: 87519
• UN Number: 2811
• UNII: SZF1OJI89D
• DSSTox Substance ID: DTXSID9059755
• Nikkaji Number: J34.861I
• Wikidata: Q26841191
• NCI Thesaurus Code: C44327
• Mol file: 194-59-2.mol

Synonyms:7H-dibenzo(c,g)carbazole

Chemical Property of 7H-Dibenzo[c,g]carbazole

Chemical Property:

• Appearance/Colour: Yellow Crystalline Solid
• Vapor Pressure: 2.39E-11mmHg at 25°C
• Melting Point: 152-154ºC
• Refractive Index: 1.86
• Boiling Point: 544.1 °C at 760 mmHg
• PKA: 17.00±0.30(Predicted)
• Flash Point: 246.5 °C
• PSA: 15.79000
• Density: 1.308 g/cm³
• LogP: 5.62750
• Storage Temp.: 2-8°C
• Solubility.: Acetonitrile (Slightly), , Chloroform (Slightly)
• Water Solubility.: 53.47ug/L(22 oC)
• XLogP3: 5.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 267.104799419
• Heavy Atom Count: 21
• Complexity: 355
• Transport DOT Label: Poison

Purity/Quality:

98%,99%, ^*data from raw suppliers

7H-Dibenzo[c,g]carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Polycyclic Aromatic Hydrocarbons
• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=C2C4=C(N3)C=CC5=CC=CC=C54
• Uses: A heterocyclic aromatic compound with potent mutagenic and carcinogenic properties A heterocyclic aromatic compound with potent mutagenic and carcinogenic properties.

Technology Process of 7H-Dibenzo[c,g]carbazole

There total 51 articles about 7H-Dibenzo[c,g]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1,1'-bi-2-naphthol (602-09-5) → 7H-dibenzo[c,g]carbazole (194-59-2)

Guidance literature:

With ammonium hydroxide; ammonium bisulfite; at 220 ℃; for 16h; Temperature; Reagent/catalyst; Autoclave;

Reference yield: 96.0%

2-amino-2’-hydroxy-1,1’-binaphthyl (134532-03-9,137848-28-3,137848-29-4) → 7H-dibenzo[c,g]carbazole (194-59-2)

Guidance literature:

With ammonium sulfite monohydrate; ammonia; In water; at 200 ℃; for 240h; Temperature; Autoclave;

DOI:10.1016/j.tetlet.2017.11.054

Reference yield: 90.0%

1,1'-binaphthalene-2,2'-diamine (4488-22-6,18531-95-8) → 7H-dibenzo[c,g]carbazole (194-59-2)

Guidance literature:

With hydrogenchloride; In acetonitrile; at 20 ℃; for 3h;

upstream raw materials:

1,1'-binaphthalene-2,2'-diamine

2,2'-dinitro-[1,1']binaphthyl

tetrahydrofuran

7H-Dibenzo[c,h]phenothiazine

Downstream raw materials:

5-nitro-7H-dibenzo[c,g]carbazole

5,9-dinitro-7H-dibenzo[c,g]carbazole

7-[4-(10-phenyl-9-anthryl)phenyl]-7H-dibenzo[c,g]carbazole

7-(4-bromophenyl)-7H-dibenzo[c,g]carbazole

Refernces

• 1、 Lim, Byong-Yun,Choi, Min-Kyung,Cho, Cheon-Gyu. "Acid-catalyzed condensation of 2,2′-diamino-1,1′-biaryls for the synthesis of benzo[c]carbazoles". . p. 6015 - 6017. Retrieved 2011.
• 2、 -. "COMPOUND AND ORGANIC LIGHT EMITTING ELEMENT COMPRISING SAME". Paragraph 0137; 0138. . Retrieved 2020/05/14.
• 3、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF". Paragraph 0134; 0140-0143; 0155-0158. . Retrieved 2020/05/30.