Divinyl adipate

Base Information

• Chemical Name: Divinyl adipate
• CAS No.: 4074-90-2
• Molecular Formula: C10H14 O4
• Molecular Weight: 198.219
• Hs Code.: 29171200
• European Community (EC) Number: 223-792-1
• UNII: D145740345
• DSSTox Substance ID: DTXSID7074248
• Nikkaji Number: J36.607B
• Wikidata: Q27275957
• Mol file: 4074-90-2.mol

Synonyms:divinyl adipate;divinyladipate

Chemical Property of Divinyl adipate

Chemical Property:

• Vapor Pressure: 0.0118mmHg at 25°C
• Melting Point: 28 °C
• Refractive Index: 1.4549
• Boiling Point: 261.1°Cat760mmHg
• Flash Point: 122.2°C
• PSA: 52.60000
• Density: 1.039g/cm³
• LogP: 1.92020
• Solubility.: soluble in Methanol
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 9
• Exact Mass: 198.08920892
• Heavy Atom Count: 14
• Complexity: 196

Purity/Quality:

98%,99%, ^*data from raw suppliers

Divinyl Adipate (stabilized with MEHQ) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=COC(=O)CCCCC(=O)OC=C

Technology Process of Divinyl adipate

There total 9 articles about Divinyl adipate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

vinyl acetate (108-05-4,9003-20-7) + Adipic acid (124-04-9) → divinyl adipate (4074-90-2)

Guidance literature:

With sulfuric acid; mercury(II) diacetate; for 4h; Reflux; Inert atmosphere;

DOI:10.1039/c0ob00304b

Reference yield: 48.0%

trimethylsiloxyethene (6213-94-1) + Adipic acid dichloride (111-50-2) → divinyl adipate (4074-90-2)

Guidance literature:

With potassium fluoride; 18-crown-6 ether; In acetonitrile; at 40 - 50 ℃; for 20h; Inert atmosphere;

DOI:10.1080/00397911.2020.1808995

Reference yield: 16.0%

Adipic acid (124-04-9) + ethene (74-85-1) → divinyl adipate (4074-90-2)

Guidance literature:

With trihexyl(tetradecyl)phosphonium chloride; tetrabutyl-ammonium chloride; copper diacetate; tetrahexylammonium chloride; palladium; copper dichloride; In 1,4-dioxane; for 21h; Catalytic behavior; High pressure;

upstream raw materials:

vinyl acetate

Adipic acid

acetaldehyde

Adipic acid dichloride

Downstream raw materials:

6-O-vinyladipoyl arbutin

troxerutin vinyl adipate

6-O-(phenyl β-D-glucopyranosyl) vinyl adipate

6-O-(p-nitrophenyl 2-acetamido-2-deoxy-β-D-glucopyranosyl) vinyl adipate

Refernces

• 1、 Hofecker, Andreas,Knaack, Patrick,Liska, Robert,Markovic, Marica,Ovsianikov, Aleksandr,Steinbauer, Patrick. "Novel synthesis routes for the preparation of low toxic vinyl ester and vinyl carbonate monomers". supporting information. p. 3629 - 3641. Retrieved 2020/10/02.
• 2、 Husar, Branislav,Heller, Christian,Schwentenwein, Martin,Mautner, Andreas,Varga, Franz,Koch, Thomas,Stampfl, Juergen,Liska, Robert. "Biomaterials based on low cytotoxic vinyl esters for bone replacement application". experimental part. p. 4927 - 4934. Retrieved 2012/06/01.