Cyclohexylazanium;bromide

Base Information

• Chemical Name: Cyclohexylazanium;bromide
• CAS No.: 26227-54-3
• Molecular Formula: C6H14BrN
• Molecular Weight: 180.088
• Hs Code.: 2921300090
• Mol file: 26227-54-3.mol

Synonyms:

Chemical Property of Cyclohexylazanium;bromide

Chemical Property:

• Vapor Pressure: 8.07mmHg at 25°C
• Melting Point: 196-199 °C
• Refractive Index: nD20 1.4585
• Boiling Point: 134.5 °C at 760 mmHg
• Flash Point: 32.2 °C
• PSA: 26.02000
• Density: 0.868 g/ml
• LogP: 2.93620
• Storage Temp.: 2-8°C
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 179.03096
• Heavy Atom Count: 8
• Complexity: 46.1

Purity/Quality:

99% ^*data from raw suppliers

CYCLOHEXYLAMINE HYDROBROMIDE ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)[NH3+].[Br-]

Technology Process of Cyclohexylazanium;bromide

There total 6 articles about Cyclohexylazanium;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trimethylsilyl bromide (2857-97-8) + t-BuPhP(S)S(1-)*(1+)NH3C6H11 (107487-34-3) → cyclohexylammonium bromide (26227-54-3) + trimethylsilyl t-butylphenyldithiophosphinate (107487-35-4)

Guidance literature:

In tetrachloromethane;

DOI:10.1016/S0040-4020(01)87438-X

Reference yield: 59.0%

[NiBr2(cyclohexylamine)4] + cyclohexylamine (108-91-8,157973-60-9) → N,N'-dicyclohexyloxamide (3299-64-7) + cyclohexylammonium bromide (26227-54-3) + 1,3-Dicyclohexylurea (2387-23-7) + tetracarbonyl nickel (13463-39-3,71564-36-8)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; diethyl ether; addn. of RNH2 to suspn. of complex, CO (40 bar), warmed up to 45°C, 20h, hydrolysis with H2SO4, sepn. of organic phase, dried, crystn. of organic products from hexane/CHCl3 = 20/1;

DOI:10.1016/S0022-328X(00)99113-7

Reference yield:

cyclohexylamine (108-91-8,157973-60-9) → cyclohexylammonium bromide (26227-54-3)

Guidance literature:

With hydrogen bromide; In water; for 0.333333h;

DOI:10.1016/j.jallcom.2017.01.032

upstream raw materials:

trimethylsilyl bromide

t-BuPhP(S)S^(1-)*⁽¹⁺⁾NH₃C₆H₁₁

1-ethyl-2-bromo-pyridinium; bromide

cyclohexylamine

Downstream raw materials:

N-cyclohexyl-N,N,N-trimethylammonium bromide

N-Cyclohexyl-N-(2-phenylethyl)amine

ethyl 2-(cyclohexylamino)propanoate

N-butylcyclohexylamine

Refernces

• 1、 Kravchenko, V. V.,Kotenko, A. A.,Popov, A. F.,Kostenko, L. I.,Vegh, D.,Kovac, J.. "EFFECT OF THE STRUCTURE OF AMINES ON RATE AND MECHANISM OF THEIR REACTIONS WITH 2-(β,β-DIBROMOVINYL)-5-NITROFURAN IN ACETONITRILE". . p. 2140 - 2143. Retrieved 2007/10/02.
• 2、 Litvinenko, L. M.,Titskii, G. D.,Mitchenko, E. S.. "KINETICS OF THE REACTIONS OF 2-HALOGENOPYRIDINIUM SALTS WITH PRIMARY AND SECONDARY AMINES IN ACETONITRILE". . p. 1731 - 1736. Retrieved 2007/10/02.