Triphenyltin hydroxide [MI]

Base Information

• Chemical Name: Triphenyltin hydroxide [MI]
• CAS No.: 76-87-9
• Molecular Formula: C18H16OSn
• Molecular Weight: 367.034
• Hs Code.: 29319090
• UNII: KKL46V5313
• Mol file: 76-87-9.mol

Synonyms:FENTIN HYDROXIDE [ISO];TRIPHENYLTIN HYDROXIDE [MI];AKOS015898673

Chemical Property of Triphenyltin hydroxide [MI]

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: 118 - 120 °C
• Boiling Point: 428.5±28.0 °C(Predicted)
• PKA: 3.98±0.70(Predicted)
• PSA: 20.23000
• Density: 1.54
• LogP: 1.64580
• Storage Temp.: APPROX 4°C
• Solubility.: Slightly soluble in alcohol, toluene
• Water Solubility.: <0.1 g/100 mL at 21℃
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 368.022318
• Heavy Atom Count: 20
• Complexity: 202

Purity/Quality:

Triphenyltin hydroxide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+; N
• Hazard Codes: T+,N
• Statements: 24/25-26-37/38-40-41-48/23-50/53-63-36/37/38
• Safety Statements: 26-28-36/37/39-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn+](C2=CC=CC=C2)C3=CC=CC=C3.[OH-]
• Uses: Triphenyltin Hydroxide is an organotin compound. Triphenyltin Hydroxide is used as a fungicide and antifeeding compound for insect control. Recent studies show that Triphenyltin Hydroxide may have adv erse effects on the reproductive and immune systems and may disrupt the endocrine system. Reactant involved in transmetalation reactions with Ir clusters. Reactant involved in synthesis of (E)-(Nitrophenyl)propenoic acid organotin(IV) carboxylates with antitumor activity, triorganotin chrysanthemumates for larvicidal studies, polynuclear organotin(IV) carboxylates containing ferrocenyl moieties for antitumor investigation, organotin(IV) aminophenylacrylate complexes, 4-Biphenylcarboxylic acid derivatives for in vitro cytotoxicity studies.

Technology Process of Triphenyltin hydroxide [MI]

There total 47 articles about Triphenyltin hydroxide [MI] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

hexaphenylditin (1064-10-4) + water (7732-18-5) + C6H5ISm (88020-61-5) → tetraphenyltin(IV) (595-90-4) + triphenyltin(IV) hydroxide (76-87-9)

Guidance literature:

In tetrahydrofuran; under Ar; addn. of freshly prepd. THF soln. of PhSmI to mixt. of THF and Ph3SnSnPh3, mixing at 25°C for 3 h, decompn. of react. mixt. with water acidified with HCl; thin layer chromy.;

Reference yield:

triphenyltin chloride (639-58-7) + sodium hydroxide (1310-73-2) → triphenyltin(IV) hydroxide (76-87-9)

Guidance literature:

In neat (no solvent, solid phase); according to B. Kushlefsky, L. Simmons, A. Ross, Inorg. Chem. 1963, 2, 187;

DOI:10.1002/zaac.200900376

Reference yield:

sodium triphenylstannide → triphenyltin(IV) hydroxide (76-87-9)

Guidance literature:

With ammonia; oxygen;

upstream raw materials:

diphenyl-bromonium; iodide

bromobenzene

tetraphenyltin(IV)

diphenylzinc

Downstream raw materials:

dicyclohexylammonium S-triphenylstannylmercaptoacetate

diphenyltin-2-mercaptobenzoate

bis(triphenyltin) mercaptoacetate

triphenylstannane

Refernces

• 1、 Glidewell, Christopher,Low, John N.,Bomfim, Joao A. S.,Filgueiras, Carlos A. L.,Wardell, James L.. "catena-poly[[triphenyltin(IV)]-μ-hydroxo-κ2O:O] at 120 K". . p. m199-m201. Retrieved 2002.
• 2、 Annissa,Suhartati, Tati,Yandri,Hadi, Sutopo. "Antibacterial activity of diphenyltin(IV) and triphenyltin(IV) 3-chlorobenzoate againts Pseudomonas aeruginosa and Bacillus subtilis". . p. 1133 - 1139. Retrieved 2017/08/01.