[(butylsulfonyl)methyl]benzene

Base Information

• Chemical Name: [(butylsulfonyl)methyl]benzene
• CAS No.: 3112-93-4
• Molecular Formula: C11H16 O2 S
• Molecular Weight: 212.313
• Mol file: 3112-93-4.mol

Synonyms:Sulfone,benzyl butyl (6CI,7CI,8CI); Benzyl butyl sulfone; Benzyl n-butyl sulfone; NSC2363

Chemical Property of [(butylsulfonyl)methyl]benzene

Chemical Property:

• Vapor Pressure: 1.39E-05mmHg at 25°C
• Boiling Point: 378.2°Cat760mmHg
• Flash Point: 221.9°C
• Density: 1.101g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [(butylsulfonyl)methyl]benzene

There total 13 articles about [(butylsulfonyl)methyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

benzyl butyl sulfide (5184-47-4) → (butylsulfonyl)methylbenzene (3112-93-4)

Guidance literature:

With benzyl(triethyl)ammoniumpermanganate; In dichloromethane; acetic acid; at -10 ℃; for 1h;

DOI:10.1007/BF00911089

Reference yield: 87.0%

N,N,N--trimethyl--1--phenylmethanaminium trifluoromethanesulfonate (260783-80-0) + butane sulfonic acid hydrazide (10393-85-8) → (butylsulfonyl)methylbenzene (3112-93-4)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; triphenylphosphine; In dimethyl sulfoxide; toluene; at 100 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1080/10426507.2021.2016758

Reference yield: 86.0%

benzyl butyl sulfide (5184-47-4) → (butylsulfonyl)methylbenzene (3112-93-4) + ((R)-Butane-1-sulfinylmethyl)-benzene (67501-09-1) + ((S)-Butane-1-sulfinylmethyl)-benzene (2844-06-6)

Guidance literature:

In ethanol; water; at 27 ℃; for 48h; Yields of byproduct given; Mortierella isabellina;

upstream raw materials:

benzyl butyl sulfide

benzyl 2-butenyl sulfone

1-Benzylsulfonyl-1,3-butadien

phenylmethanethiol

Downstream raw materials:

C₁₈H₂₀O₂S

Refernces

• 1、 Deeming, Alex S.,Russell, Claire J.,Hennessy, Alan J.,Willis, Michael C.. "DABSO-based, three-component, one-pot sulfone synthesis". supporting information. p. 150 - 153. Retrieved 2014/01/23.
• 2、 Jereb, Marjan. "Highly atom-economic, catalyst- and solvent-free oxidation of sulfides into sulfones using 30% aqueous H2O2". supporting information. p. 3047 - 3052,6. Retrieved 2020/09/16.