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CAS No.: | 5919-74-4 |
---|---|
Name: | 2,3-DIHYDROXYPROPYL METHACRYLATE |
Article Data: | 21 |
Molecular Structure: | |
Formula: | C7H12O4 |
Molecular Weight: | 160.17 |
Synonyms: | Methacrylicacid, 2,3-dihydroxypropyl ester (6CI);Methacrylin, 1-mono- (8CI);2,3-Dihydroxypropyl methacrylate;Glyceryl methacrylate; |
EINECS: | 227-642-6 |
Density: | 1.161 g/cm3 |
Melting Point: | 140℃/0.6mm |
Boiling Point: | 310.3 °C at 760 mmHg |
Flash Point: | 127.3 °C |
Solubility: | 100g/L at 25℃ |
Risk Codes: | 36/37/38 |
Safety: | 26-36 |
PSA: | 66.76000 |
LogP: | -0.54110 |
Conditions | Yield |
---|---|
With Cs2.5H0.5PMo12O40; water In tetrahydrofuran at 35 - 70℃; for 4h; Reagent/catalyst; | 93.2% |
With sulfuric acid; water In tetrahydrofuran for 2h; Ambient temperature; | 88% |
With sulfuric acid; 4-tert-Butylcatechol In water for 24h; Ambient temperature; | 70% |
2-methyl-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester
2,3-dihydroxypropyl methacrylate
Conditions | Yield |
---|---|
With acetic acid; 4-methoxy-phenol at 80℃; for 0.166667h; | 80% |
Hydrolysis; Acid hydrolysis; | |
With hydrogenchloride; water at 20℃; for 48h; Industry scale; Air stream; | |
With methanol; TEMPOL; 4-methoxy-phenol at 65℃; for 20h; Reagent/catalyst; Temperature; | 73.1 %Chromat. |
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol
Methacryloyl chloride
2,3-dihydroxypropyl methacrylate
Conditions | Yield |
---|---|
With triethylamine In chloroform cooling; |
methacrylic acid methyl ester
glycerol
B
2,3-dihydroxypropyl methacrylate
C
glycerol-1,3-dimethacrylate
Conditions | Yield |
---|---|
With Novozyme 435 In tert-Amyl alcohol at 50℃; for 120h; Inert atmosphere; Molecular sieve; Enzymatic reaction; |
poly(methacrylic acid)
glycerol
A
glyceryl tri(methyl)acrylate
B
2,3-dihydroxypropyl methacrylate
C
glycerol-1,3-dimethacrylate
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid; p-benzoquinone at 90℃; |
Conditions | Yield |
---|---|
With water at 10 - 50℃; for 5h; Green chemistry; Overall yield = 22.0 g; | |
With 2,6-di-tert-butyl-4-methyl-phenol; water at 70℃; for 2.5h; Overall yield = 98 %; |
Conditions | Yield |
---|---|
In methanol; water at 20℃; for 1h; Kinetics; Irradiation; |
Conditions | Yield |
---|---|
With N,N,N,N,-tetramethylethylenediamine; 2,6-di-tert-butyl-4-methyl-phenol In dichloromethane at -78℃; for 5h; | 92% |
Conditions | Yield |
---|---|
dibutyltin dilaurate In tetrahydrofuran at 50℃; for 5h; | 90% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In cyclohexane Reflux; Dean-Stark; | 66% |
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This chemical is called 2-Propenoic acid,2-methyl-, 2,3-dihydroxypropyl ester, and it can also be named as Glyceryl methacrylate. With the molecular formula of C7H12O4, its molecular weight is 160.17. The CAS registry number of this chemical is 5919-74-4. Additionally, its product category is Monomer.
Other characteristics of the 2-Propenoic acid,2-methyl-, 2,3-dihydroxypropyl ester can be summarised as followings: (1)ACD/LogP: -0.12; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.12; (4)ACD/LogD (pH 7.4): -0.12; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 20.4; (8)ACD/KOC (pH 7.4): 20.4; (9)#H bond acceptors: 4; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 7; (12)Polar Surface Area: 44.76 Å2; (13)Index of Refraction: 1.475; (14)Molar Refractivity: 38.85 cm3; (15)Molar Volume: 137.8 cm3; (16)Polarizability: 15.4×10-24cm3; (17)Surface Tension: 42.2 dyne/cm; (18)Density: 1.161 g/cm3; (19)Flash Point: 127.3 °C; (20)Enthalpy of Vaporization: 63.91 kJ/mol; (21)Boiling Point: 310.3 °C at 760 mmHg; (22)Vapour Pressure: 5.43E-05 mmHg at 25°C.
You can still convert the following datas into molecular structure:
1.SMILES: O=C(OCC(O)CO)\C(=C)C
2.InChI: InChI=1/C7H12O4/c1-5(2)7(10)11-4-6(9)3-8/h6,8-9H,1,3-4H2,2H3
3.InChIKey: QRIMLDXJAPZHJE-UHFFFAOYAY