IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER

Base Information

• Chemical Name: IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER
• CAS No.: 12582-61-5
• Molecular Formula: C88H56 Fe2 N8 O
• Molecular Weight: 1353.16
• Mol file: 12582-61-5.mol

Synonyms:Iron,m-oxobis[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]di-;Iron, m-oxobis[5,10,15,20-tetraphenylporphinato(2-)]di-(8CI); 21H,23H-Porphine, 5,10,15,20-tetraphenyl-, iron complex;21H,23H-Porphine, iron deriv.; Bis(meso-tetraphenylporphyrinate)oxodiiron;Oxobis(meso-tetraphenylporphinatoiron); Oxobis(tetraphenylporphyrinato)diiron;Oxobis[(tetraphenylporphyrinato)iron]; m-Oxo-bis[(5,10,15,20-tetraphenylporphyrinato)iron(III)];m-Oxobis(tetraphenylporphyriniron(III)); m-Oxobis(tetraphenylporphyrin)diiron;m-Oxobis[(5,10,15,20-tetraphenylporphyrinato)iron];m-Oxobis[(meso-tetraphenylporphinato)iron];m-Oxobis[(tetraphenylporphyrinato)iron];m-Oxobis[a,b,g,d-tetraphenylporphinatoiron(III)];m-Oxobis[a,b,g,d-tetraphenylporphyrinato(2-)]diiron

Chemical Property of IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 78.39000
• Density: g/cm³
• LogP: 12.80220
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Water Solubility.: Insoluble in water.

Purity/Quality:

99% ^*data from raw suppliers

Iron(III) meso-tetraphenylporphine-μ-oxo dimer ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Iron(III) meso-tetraphenylporphine-μ-oxo dimer used as catalyst.

Technology Process of IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER

There total 44 articles about IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) → ((5,10,15,20-tetraphenylporphyrinato)iron(III))2O (12582-61-5)

Guidance literature:

With sodium hydroxide; In dichloromethane; water; shaking the CH2Cl2-soln. of (FeTPP)Cl with aq. 2 M NaOH (3 times), 10 min; washing the CH2Cl2-layer (H2O), evapn. (N2, 40°C), taken up in benzene, chromatography (silicic acid column);

DOI:10.1021/ja00224a006

Reference yield:

iron(II)(tetraphenylporphyrin)(pyridine)(i-Pr-NO) (84027-23-6,64479-14-7) → ((5,10,15,20-tetraphenylporphyrinato)iron(III))2O (12582-61-5)

Guidance literature:

With air; In N,N-dimethyl-formamide; 27°C; Kinetics;

DOI:10.1021/ja00341a027

Reference yield:

COFe(C44H28N4)C3H4N2 (41754-43-2) → μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron] (12582-61-5)

Guidance literature:

With oxygen; In benzene;

DOI:10.1021/ja00787a075

upstream raw materials:

(tetraphenylporphyrin)Fe(CH₃)

COFe(C₄₄H₂₈N₄)C₃H₄N₂

cetyltrimethylammonim bromide

meso-tetraphenylporphyrin iron(III) chloride

Downstream raw materials:

thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II)

5,10,15,20-tetraphenyl porphyrin iron

meso-tetraphenylporphyrinatobis(pyridine)iron(II)

azido(tetraphenylporphyrinato)iron(III)

Refernces

• 1、 Evans, Daniel R.,Reed, Christopher A.. "Reversal of H2O and OH- ligand field strength on the magnetochemical series relative to the spectrochemical series. Novel 1-equiv water chemistry of iron(III) tetraphenylporphyrin complexes". . p. 4660 - 4667. Retrieved 2000.
• 2、 Guerin, Philippe,Battioni, Jean-Paul,Chottard, Jean-Claude,Mansuy, Daniel. "COMPLEXES DE LA FERROTETRAPHENYLPORPHYRINE AVEC DES HALOGENOALKYLCARBENES: Fe". . p. 201 - 209. Retrieved 1981.
• 3、 Hubbard, Colin D.,Jones, John G.. "". . p. 71 - 76. Retrieved 1986.
• 4、 Hubbard, Colin D.,Jones, John G.,McKnight, John. "The oxidation of bromide ion by [(FeTPP)2O]+SbF6- In dichloromethanej". . p. 3143 - 3148. Retrieved 2000.
• 5、 Wolowiec, S.,Kochi, J. K.. "Spontaneous Formation of Reactive Oxometal Porphyrins by Oxygen Atom Transfer from Dioxirane". . p. 1782 - 1784. Retrieved 1990.
• 6、 Shin, Koo,Goff, Harold M.. "". . p. 3140 - 3142. Retrieved 1987.
• 7、 Xu, Nan,Goodrich, Lauren E.,Lehnert, Nicolai,Powell, Douglas R.,Richter-Addo, George B.. "Five- and six-coordinate adducts of nitrosamines with ferric porphyrins: Structural models for the type II interactions of nitrosamines with ferric cytochrome P450". . p. 4405 - 4419. Retrieved 2010/07/04.
• 8、 Hu, Chuanjiang,Noll, Bruce C.,Scheidt, W. Robert. "Sulfoxide as a ligand in iron(II) porphyrinates: S- or O-bound?". . p. 8258 - 8263. Retrieved 2008/10/09.