iron(II) tetraphenylporphyrin thiocarbonyl

Base Information

• Chemical Name: iron(II) tetraphenylporphyrin thiocarbonyl
• CAS No.: 67583-11-3
• Molecular Formula: 0CH₂Cl₂*C₄₅H₂₈FeN₄S
• Molecular Weight: 723.274
• Mol file: 67583-11-3.mol

Synonyms:

Chemical Property of iron(II) tetraphenylporphyrin thiocarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of iron(II) tetraphenylporphyrin thiocarbonyl

There total 10 articles about iron(II) tetraphenylporphyrin thiocarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

iron(II) tetraphenylporphyrin (thiobenzyl)chlorocarbene (80697-74-1) → thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II) (67583-11-3)

Guidance literature:

In chloroform-d1; 20 h at 20°C; detd. by NMR spectrum;

DOI:10.1021/ic00135a066

Reference yield: 50.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) + trichloromethyltrimethylsilane (5936-98-1) → μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV)) (75249-87-5) + thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II) (67583-11-3)

Guidance literature:

With Aliquat 336; In water; toluene; stirred 2 h, soln. evaporated;

DOI:10.1016/S0022-328X(81)80004-6

Reference yield: 12.0%

C20H12N4FeCFeC20H12N4 + trichloromethyltrimethylsilane (5936-98-1) → μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV)) (75249-87-5) + thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II) (67583-11-3)

Guidance literature:

With sodium dithionite; Aliquat 336; In water; toluene; stirred 2 h; recrystd. from CH2Cl2/CH3OH;

DOI:10.1016/S0022-328X(81)80004-6

upstream raw materials:

Fe(C₄₄H₂₈N₄)(CS)(C₂H₅OH)

thiophosgene

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron]

trichloromethyltrimethylsilane

Downstream raw materials:

(C(C₆H₅)C₄H₂N)4FeCS(CH₃OH)

Fe[TPP][CS](n-C₄H₉S)^(1-)

(C(C₆H₅)C₄H₂N)4FeCS(NH₂CH(CH₃)2)

(C(C₆H₅)C₄H₂N)4FeCS(P(CH₂CH₃)3)

Refernces

• 1、 Bottomley, Lawrence A.,Deakin, Mark R.,Gorce, Jean-Noel. "Oxidative electrochemistry of iron thiocarbonyl porphyrins". . p. 3563 - 3571. Retrieved 2008/10/08.
• 2、 Battoni, Jean-Paul,Dupre, Daniel,Mansuy, Daniel. "REACTIONS DU TRICHLOROMETHYL-TRIMETHYL-SILANE AVEC DES FERROTETRA-ARYL-PORPHYRINES". . p. 303 - 309. Retrieved 2007/10/02.