{bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}

Base Information

• Chemical Name: {bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}
• CAS No.: 52542-59-3
• Molecular Formula: C₅MnO₅*C₃₆H₃₀NP₂
• Molecular Weight: 733.578
• Mol file: 52542-59-3.mol

Synonyms:{bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}

Chemical Property of {bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of {bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}

There total 16 articles about {bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(C6H5)3PNP(C6H5)3(1+)*(CO)4MnCOCH(C6H5)OCO(1-)=(C6H5)3PNP(C6H5)3(CO)4MnCOCH(C6H5)OCO (68433-31-8) → bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + 1-benzylidene-2-(2,4-dinitrophenyl)hydrazone (1157-84-2)

Guidance literature:

In tetrahydrofuran; soln. of complex in THF was refluxed for 6 days, cooled to room temp. (N2 atm.); cooled at -20°C for 2 h; ppt. was filtered, C6H5CHO was in the filtrate;

DOI:10.1021/ja00267a015

Reference yield: 13.0%

(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate (75008-28-5) + bis(triphenylphosphine)iminium chloride (21050-13-5) + bis(triphenylphosphoranylidene)ammonium nitrite → bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5)

Guidance literature:

With Na#Hg; In tetrahydrofuran; under N2 or Ar; THF added to mixt. ((Ph3P)2N)NO2/(Mn(CO)5(CH3CN))BF4, stirring; soln. distd. in vac. into flask containing excess of Na#Hg at -195°C; warmed to room temp., stirred for 19 h; Hg sepd. with filtration; ((C6H5)3P)2)NCl/THF added; filtered; recrystd. from THF/petroleum ether (30-60°C);

DOI:10.1016/S0020-1693(99)00546-0

Reference yield:

dimanganese decacarbonyl (10170-69-1) + {bis(triphenylphosphine)nitrogen}2{(iron)3(carbonyl)11} (66039-65-4) → triiron dodecarbonyl (17685-52-8) + bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5)

Guidance literature:

In tetrahydrofuran; under inert atmosphere, at 25°C; IR; Kinetics;

upstream raw materials:

[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Re(CO)5]

(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate

bis(triphenylphosphine)iminium chloride

dimanganese decacarbonyl

Downstream raw materials:

((C₆H₅)3P)2N⁽¹⁺⁾*Mn₂(SCF₃)3(CO)6^(1-)=(((C₆H₅)3P)2N)Mn₂(SCF₃)3(CO)6

((C₆H₅)3P)2N⁽¹⁺⁾*Mn(SCF₃)2(CO)4^(1-)=(((C₆H₅)3P)2N)Mn(SCF₃)2(CO)4

iron pentacarbonyl

dimanganese decacarbonyl

Refernces

• 1、 Yoon,Park,Kochi. "Interfacial electron transfer to the zeolite-encapsulated methylviologen acceptor from various carbonylmanganate donors. Shape selectivity of cations in mediating electron conduction through the zeolite framework". . p. 12710 - 12718. Retrieved 2007/10/03.
• 2、 Shauna Corraine,Atwood, Jim D.. "Electron transfer between mononuclear metal carbonyl anions (M(CO)5-, M = Mn, Re; CpFe(CO)2-; CpM(CO)3-, M = Cr, Mo) and trinuclear clusters (M3(CO)12, M = Fe, Ru, Os) and between trinuclear dianions (M3(CO)112-, M = Fe, Ru, Os) and metal carbonyl dimers (Mn ...". . p. 2647 - 2651. Retrieved 2008/10/08.