o-(Prop-2-enyloxy)phenyllead Triacetate

Base Information

• Chemical Name: o-(Prop-2-enyloxy)phenyllead Triacetate
• CAS No.: 151414-77-6
• Molecular Formula: C₁₅H₁₈O₇Pb
• Molecular Weight: 517.504
• Mol file: 151414-77-6.mol

Synonyms:o-(Prop-2-enyloxy)phenyllead Triacetate

Chemical Property of o-(Prop-2-enyloxy)phenyllead Triacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of o-(Prop-2-enyloxy)phenyllead Triacetate

There total 1 articles about o-(Prop-2-enyloxy)phenyllead Triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

mercury(II) diacetate (1600-27-7) + lead(IV) tetraacetate (546-67-8) + o-(prop-2-enyloxy)phenylboronic acid (151414-76-5) → o-(Prop-2-enyloxy)phenyllead Triacetate (151414-77-6)

Guidance literature:

In chloroform; to a soln. of Pb(OAc)4 and Hg(OAc)2 in CHCl3 is added the arylboronic acid, the mixt. is stirred at 40°C for 1 h and then 12 h at room temp.; the mixt. is filtered through Celite and washed with CHCl3, the CHCl3-soln. is washed with H2O and the aq. layer is reextracted with CHCl3, light petroleum is added, the ppt. is collected at 0°C, crystn. from CHCl3/light petroleum, elem. anal.;

DOI:10.1039/P19930001673

Reference yield: 90.0%

2-ethoxycarbonyl-1-cyclopentanone (611-10-9) + o-(Prop-2-enyloxy)phenyllead Triacetate (151414-77-6) → ethyl 2-oxo-1-cyclopentanecarboxylate

Guidance literature:

With pyridine; In chloroform; 1) 40 deg C, 1 h, 2) r.t., overnight;

DOI:10.1039/P19930001673

Reference yield: 74.0%

sodium azide + o-(Prop-2-enyloxy)phenyllead Triacetate (151414-77-6) → o-(prop-2-enyloxy)phenyl azide (55000-07-2)

Guidance literature:

In dimethyl sulfoxide; a mixt. of NaN3 and aryllead triacetate in dry DMSO is stirred for 2.5 h in the dark at room temp.; the residual after work-up is filtered, with protection from light, through a column of silica gel, elution with with light petroleum;

DOI:10.1039/P19930001673

upstream raw materials:

mercury(II) diacetate

lead(IV) tetraacetate

o-(prop-2-enyloxy)phenylboronic acid

Downstream raw materials:

acetic acid 1-methyl-2-oxo-2-phenyl-ethyl ester

1-phenyl-propan-1-one

1-allyloxy-2-iodobenzene

o-(prop-2-enyloxy)phenyl azide

Refernces