cis-1-decalone

Base Information

• Chemical Name: cis-1-decalone
• CAS No.: 32166-40-8
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.236
• Mol file: 32166-40-8.mol

Synonyms:cis-1-decalone

Chemical Property of cis-1-decalone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-1-decalone

There total 15 articles about cis-1-decalone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

cis-decalin (493-01-6) → cis-9,10-decalinediol (28795-95-1) + cis-9-decalol (3574-58-1) + cis-1-decalone (32166-40-8) + cis-2-decalone (1579-21-1)

Guidance literature:

With methyltrifluoromethyldioxirane; In dichloromethane; at -22 ℃; for 0.0833333h; Yields of byproduct given;

DOI:10.1021/ja00199a039

Reference yield: 34.0%

3-(4-Iodo-butyl)-cyclohex-2-enone (130660-16-1) → cis-1-decalone (32166-40-8) + 3-(4-Iodobutyl)cyclohexan-1-one (130660-18-3)

Guidance literature:

With hydrido(triphenylphosphine)copper(I) hexamer; In tetrahydrofuran; for 24h; Ambient temperature;

DOI:10.1016/S0040-4039(00)89032-2

Reference yield: 10.0%

(E)-10-Iododeca-1,6-dien-3-one (155511-10-7) → trans-1-decalone (21370-71-8) + cis-1-decalone (32166-40-8) + (E)-Deca-1,6-dien-3-one

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 0.5h; Yield given. Yields of byproduct given; Heating;

DOI:10.1016/0040-4039(94)85233-2

upstream raw materials:

3,4,5,6,7,8-hexahydro-2H-naphthalen-1-one

cis-decalin

3-(4-Iodo-butyl)-cyclohex-2-enone

2-(4-Bromobutyl)-2-cyclohexen-1-one

Downstream raw materials:

(+/-)-2-((E)-4-chloro-benzyliden)-(4ar,8at)-octahydro-naphthalen-1-one

(1RS,4aRS,8aSR)-decahydronaphthalen-1-ol

2-benzyliden-octahydro-naphthalen-1-one

(+/-)-4-oxo-4ar-methyl-3-(benzylidene-(seqtrans))-(8acH)-decalin

Refernces

• 1、 Mettry, Magi,Moehlig, Melissa Padilla,Gill, Adam D.,Hooley, Richard J.. "Alkane oxidation catalysed by a self-folded multi-iron complex". . p. 120 - 128. Retrieved 2016/11/09.
• 2、 Tangestaninejad,Habibi,Mirkhani,Moghadam. "Mn (Br8TPPS) supported on Amberlite IRA-400 as a robust and efficient catalyst for alkene epoxidation and alkane hydroxylation". . p. 264 - 270. Retrieved 2007/10/03.