diphenylbismuth(III) chloride

Base Information

• Chemical Name: diphenylbismuth(III) chloride
• CAS No.: 5153-28-6
• Molecular Formula: C₁₂H₁₀BiCl
• Molecular Weight: 398.645
• Mol file: 5153-28-6.mol

Synonyms:diphenylbismuth(III) chloride

Chemical Property of diphenylbismuth(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of diphenylbismuth(III) chloride

There total 46 articles about diphenylbismuth(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bismuth(III) chloride (7787-60-2) + triphenylbismuthane (603-33-8) → diphenylbismuth(III) chloride (5153-28-6)

Guidance literature:

In diethyl ether; 20°C;

DOI:10.1039/CT9222100104 DOI:10.1039/CT9150700016 DOI:10.1039/CT9242500864

Reference yield: 80.0%

thallium (III) chloride (13453-32-2) + triphenylbismuthane (603-33-8) → diphenylbismuth(III) chloride (5153-28-6)

Guidance literature:

In diethyl ether; byproducts: (C6H5)2TlCl; 20°C;

DOI:10.1039/CT9242500864 DOI:10.1039/CT9222100036

Reference yield: 72.0%

triphenylbismuthane (603-33-8) → diphenylbismuth(III) chloride (5153-28-6)

Guidance literature:

With copper dichloride; In diethyl ether; byproducts: CuCl, C6H5Cl; extn. with benzene;

DOI:10.1039/CT9222100104

upstream raw materials:

chloroform

triphenylbismuthane

tetrachloromethane

benzoyl chloride

Downstream raw materials:

biphenyl

bismuth

triphenylbismuthane

magnesium chloride

Refernces

• 1、 Luqman, Ahmad,Blair, Victoria L.,Andrews, Philip C.,Brammananth, Rajini,Crellin, Paul K.,Coppel, Ross L.. "Homo- And heteroleptic bismuth(iii/v) thiolates from N-heterocyclic thiones: Synthesis, structure and anti-microbial activity". . p. 14362 - 14377. Retrieved 2015/04/14.
• 2、 Moiseev, Dmitry V.,Malysheva, Yulia B.,Shavyrin, Andrey S.,Kurskii, Yury A.,Gushchin, Aleksey V.. "Study of homo- and cross-coupling competition in the reaction of triarylbismuth(V) dicarboxylates with methyl acrylate in the presence of a palladium catalyst". . p. 3652 - 3663. Retrieved 2007/10/03.