1,1-Dibromo-2-phenoxycyclopropan

Base Information

• Chemical Name: 1,1-Dibromo-2-phenoxycyclopropan
• CAS No.: 54061-22-2
• Molecular Formula: C₉H₈Br₂O
• Molecular Weight: 291.97
• Mol file: 54061-22-2.mol

Synonyms:1,1-Dibromo-2-phenoxycyclopropan

Chemical Property of 1,1-Dibromo-2-phenoxycyclopropan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1-Dibromo-2-phenoxycyclopropan

There total 2 articles about 1,1-Dibromo-2-phenoxycyclopropan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

Bromoform (75-25-2) + vinyl phenyl ether (766-94-9) → 1,1-Dibromo-2-phenoxycyclopropan (54061-22-2)

Guidance literature:

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In water; at 40 ℃; for 5h;

DOI:10.1002/hlca.19950780509

Reference yield:

dibromocarbene (135226-15-2,4371-77-1) + vinyl phenyl ether (766-94-9) → 1,1-Dibromo-2-phenoxycyclopropan (54061-22-2)

Guidance literature:

Reference yield:

1,1-Dibromo-2-phenoxycyclopropan (54061-22-2) → 2,2'-Diphenoxy-1,1'-bi(cyclopropyliden)

Guidance literature:

With n-butyllithium; copper dichloride; In tetrahydrofuran; hexane; at -95 ℃; for 1h;

DOI:10.1002/hlca.19950780509

upstream raw materials:

dibromocarbene

vinyl phenyl ether

Bromoform

Downstream raw materials:

C₁₁H₁₁BrO₃

Acetic acid 2-bromo-1-phenoxy-allyl ester

Refernces

• 1、 Loosli, Thomas,Borer, Markus,Kulakowska, Iga,Minger, Andrea,Neuenschwander, Markus,Engel, Peter. "Kupfer(II)-chlorid-katalysierte 'Carben-Dimerisierung' von 1-Halogeno-1-lithiocyclopropanen: Ein einfacher Zugang zu Bi(cyclopropylidenen)". . p. 1144 - 1165. Retrieved 2007/10/02.