[Rh(meso-tetramesitylporphyrinato)(CN)(CNCH₂SiMe₃)]

Base Information

• Chemical Name: [Rh(meso-tetramesitylporphyrinato)(CN)(CNCH₂SiMe₃)]
• CAS No.: 915085-32-4
• Molecular Formula: C₆₂H₆₃N₆RhSi
• Molecular Weight: 1023.21
• Mol file: 915085-32-4.mol

Synonyms:

Chemical Property of [Rh(meso-tetramesitylporphyrinato)(CN)(CNCH₂SiMe₃)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [Rh(meso-tetramesitylporphyrinato)(CN)(CNCH₂SiMe₃)]

There total 2 articles about [Rh(meso-tetramesitylporphyrinato)(CN)(CNCH₂SiMe₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) + trimethylsilylmethyl isocyanide (30718-17-3) → (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate)rhodium(III) methyl + [Rh(meso-tetramesitylporphyrinato)(CN)(CNCH2SiMe3)] (915085-32-4) + [Rh(meso-tetramesitylporphyrinato)(CN)]

Guidance literature:

In not given; for 0.5 h at room temp.;

DOI:10.1021/om0605276

Reference yield: 12.0%

pyridine (110-86-1) + 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) + trimethylsilylmethyl isocyanide (30718-17-3) → (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate)rhodium(III) methyl + (pyridine)Rh(5,10,15,20-tetramesitylporphyrinato)CN (823835-01-4) + [Rh(meso-tetramesitylporphyrinato)(CN)(CNCH2SiMe3)] (915085-32-4)

Guidance literature:

In not given; C5H5N added to a soln. of Rh complex at room temp., (CH3)3SiCH2NC added,stirred at room temp. for 1 h under N2 in the absence of light; chromd. (silica gel, hexane/CH2Cl2);

DOI:10.1021/om0605276

upstream raw materials:

pyridine

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

trimethylsilylmethyl isocyanide

Refernces