dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate

Base Information

• Chemical Name: dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate
• CAS No.: 1435349-66-8
• Molecular Formula: CF₃O₃S*C₅₃H₄₄F₃FeNO₃P₃PtS
• Molecular Weight: 1324.92
• Mol file: 1435349-66-8.mol

Synonyms:

Chemical Property of dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate

There total 1 articles about dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride (104413-90-3) + silver trifluoromethanesulfonate (2923-28-6) + diphenyl-(6-methyl-pyridin-2-yl)phosphine (132682-77-0) → dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate + dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate (1435349-66-8,1435349-69-1)

Guidance literature:

[1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride; silver trifluoromethanesulfonate; In dichloromethane; for 3h; Schlenk technique; Glovebox; Darkness;

diphenyl-(6-methyl-pyridin-2-yl)phosphine; In dichloromethane; Overall yield = 90 %; Overall yield = 354 mg; Schlenk technique; Glovebox;

DOI:10.1039/c3dt32395a

Reference yield:

dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate + dppf(2-(diphenylphosphino)-6-methylpyridine)platinum(II)bistriflate (1435349-66-8,1435349-69-1) + hydrogen (1333-74-0) → dppf(2-(diphenylphosphino)-6-methylpyridine)-hydridoplatinum(II)bis-triflate + dppf(2-(diphenylphosphino)-6-methylpyridine)-hydridoplatinum(II)bis-triflate

Guidance literature:

With diethylamine; In dichloromethane; at 40 ℃; under 3000.3 Torr; Overall yield = 93 %; Overall yield = 93 mg; Inert atmosphere; High pressure;

DOI:10.1039/c3dt32395a

upstream raw materials:

[1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride

silver trifluoromethanesulfonate

diphenyl-(6-methyl-pyridin-2-yl)phosphine

Refernces