Re(NC₆H₅)Cl₂(P(C₆H₅)3)(NC₅H₄C(CH₃)NO)

Base Information

• Chemical Name: Re(NC₆H₅)Cl₂(P(C₆H₅)3)(NC₅H₄C(CH₃)NO)
• CAS No.: 847831-83-8
• Molecular Formula: C₃₁H₂₇Cl₂N₃OPRe
• Molecular Weight: 745.662
• Mol file: 847831-83-8.mol

Synonyms:

Chemical Property of Re(NC₆H₅)Cl₂(P(C₆H₅)3)(NC₅H₄C(CH₃)NO)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Re(NC₆H₅)Cl₂(P(C₆H₅)3)(NC₅H₄C(CH₃)NO)

There total 1 articles about Re(NC₆H₅)Cl₂(P(C₆H₅)3)(NC₅H₄C(CH₃)NO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trichloro(phenylimido)bis(triphenylphosphine)rhenium(V) + 1-pyridin-2-yl-ethanone oxime (1758-54-9,79462-42-3,81563-77-1) → Re(NC6H5)Cl2(P(C6H5)3)(NC5H4C(CH3)NO) (847831-83-8)

Guidance literature:

In dichloromethane; ligand (1.6 equiv.) added to soln. of Re complex in CH2Cl2; stirred at room temp. for 3 h; concd.; subjected to colunm chromy. (silica gel, CH2Cl2, benzene-MeCN 25:1); yellowish green band collected; solvent removed under reduced pressure; dried in vac. (fused CaCl2); elem. anal.;

DOI:10.1021/ic0486116

upstream raw materials:

1-pyridin-2-yl-ethanone oxime

Refernces