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Rhodium trichloride

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Name

Rhodium trichloride

EINECS 233-165-4
CAS No. 10049-07-7 Density 5.38 g/cm3
PSA 0.00000 LogP -8.98800
Solubility Insoluble in water. Soluble in hydroxide and cyanide solutions. Melting Point 450 °C
Formula RhCl3 Boiling Point 717 °C (730 mmHg)
Molecular Weight 365.108 Flash Point N/A
Transport Information N/A Appearance black crystalline powder
Safety 36/39-26-24 Risk Codes 22-41
Molecular Structure Molecular Structure of 10049-07-7 (Rhodium trichloride) Hazard Symbols HarmfulXn
Synonyms

Rhodiumchloride;Rhodium(3+) chloride;Rhodium(III) chloride;Trichlororhodium;

Article Data 46

Rhodium trichloride Synthetic route

7782-50-5

chlorine

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) finely divided metallic Rh is heated in dry Cl2 at to 540 °C ;;100%
In neat (no solvent) Kinetics; exposing Rh to flowing Cl2 (0.05-0.80 atm) at 300-1150°C;
In neat (no solvent) rhodium black is heated at 800 °C in dry Cl2 and cooled slowly inflowing Cl2;;

rhodium(III) chloride trihydrate

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In solid in air or in Ar atmosphere; TG and DTA monitoring, X-ray diffraction anal.;
7719-12-2, 52843-90-0

phosphorus trichloride

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating;;
In not given heating;
In neat (no solvent) heating;;
10026-13-8, 874483-75-7

phosphorus pentachloride

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating with Rh;;
In not given heating;

di(rhodium)tetracarbonyl dichloride

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide In propan-1-ol Kinetics; byproducts: CO, CO2, H2O; oxidation of {Rh(CO)2Cl}2 with H2O2 in propanol contg. HCl is investigated, intermediate discussed; reaction monitored by UV/VIS spectroscopy;
With hydrogenchloride; dihydrogen peroxide In methanol Kinetics; byproducts: CO, CO2, H2O; oxidation of {Rh(CO)2Cl}2 with H2O2 in methanol contg. HCl is investigated, intermediate discussed; reaction monitored by UV/VIS spectroscopy;
With hydrogenchloride; dihydrogen peroxide In ethanol Kinetics; byproducts: CO, CO2, H2O; oxidation of {Rh(CO)2Cl}2 with H2O2 in ethanol contg. HCl is investigated, intermediate discussed; reaction monitored by UV/VIS spectroscopy;
7782-50-5

chlorine

7647-14-5

sodium chloride

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) mixt. of Rh and NaCl in Cl2 stream (red heat);;
7782-50-5

chlorine

A

Rh2Cl5

B

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating finely divided Rh in a Cl2-stream;;

tripotassium hexachlororhodate(III) monohydrate

A

potassium chloride

B

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) Kinetics; heating in dry HCl-stream; loss of water proceeds slowly at 360 °C, rapidly at 440 °C to form insol. RhCl3;; KCl is leached by water;;

tripotassium hexachlororhodate(III) monohydrate

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) Kinetics; dried K3(RhCl6)*H2O (105-110 °C); heating to 440 °C in a dry Cl2-stream;; washing with water;;

rhodium(VI) oxide hydrate

10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In hydrogenchloride byproducts: Cl2;
In hydrogenchloride byproducts: Cl2;

Rhodium trichloride Chemical Properties

Molecular structure of Rhodium trichloride (CAS NO.10049-07-7) is:

Product Name: Rhodium trichloride
CAS Registry Number: 10049-07-7
IUPAC Name: Trichlororhodium
Molecular Weight: 209.2645 [g/mol]
Molecular Formula: Cl3Rh
H-Bond Donor: 0
H-Bond Acceptor: 0 
EINECS: 233-165-4
Melting Point: 450 °C  
Boiling point 717 °C (730 mmHg)
Sensitive: Hygroscopic
Density: 5.38 g/cm3
Sensitive: Hygroscopic
Product categories: Inorganics;Chemical Synthesis;Rhodium Salts;Rhodium Metal and Ceramic Science;Catalysis and Inorganic Chemistry
Canonical SMILES: Cl[Rh](Cl)Cl
InChI: InChI=1S/3ClH.Rh/h3*1H;/q;;;+3/p-3
InChIKey: SONJTKJMTWTJCT-UHFFFAOYSA-K

Rhodium trichloride Uses

 Rhodium trichloride (CAS NO.10049-07-7) can be used as catalysts.

Rhodium trichloride Production

 Rhodium trichloride (CAS NO.10049-07-7) is produced by the action of hydrochloric acid on hydrated rhodium(III) oxide. RhCl3(H2O)3 can be crystallized from a solution in concentrated hydrochloric acid. This method helps to remove nitrogen-containing impurities. RhCl3 is prepared by reaction of chlorine with rhodium sponge at 200-300°C. The corresponding reaction in molten sodium chloride affords Na3RhCl6.

Rhodium trichloride Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD10 intraperitoneal 879mg/kg (879mg/kg)   Journal of Medicinal Chemistry. Vol. 20, Pg. 943, 1977.
rabbit LD50 intravenous 215mg/kg (215mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
Toxicology and Applied Pharmacology. Vol. 21, Pg. 589, 1972.
rat LD50 intraperitoneal 280mg/kg (280mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 intravenous 198mg/kg (198mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
Toxicology and Applied Pharmacology. Vol. 21, Pg. 589, 1972.
rat LD50 oral 1302mg/kg (1302mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(7), Pg. 55, 1977.

Rhodium trichloride Safety Profile

Safty information about Rhodium trichloride (CAS NO.10049-07-7) is:
Hazard Codes: HarmfulXn
Risk Statements: 22-41 
R22:Harmful if swallowed. 
R41:Risk of serious damage to the eyes.
Safety Statements: 36/39-26-24 
S36/39:Wear suitable protective clothing and eye/face protection. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S24:Avoid contact with skin.
WGK Germany: 3
RTECS: VI9275000
F: 21

Rhodium trichloride Specification

 Rhodium trichloride , its cas register number is 10049-07-7. It also can be called Rhodium chloride ; Rhodium chloride (RhCl3)  ; Rhodium(III) chloride (1:3) .It is a black crystalline powder. It is hazardous,so the first aid measures and others should be known. It is soluble in water to give reddish solutions that, depending on the age of the solution, contain varying proportions of RhCl3(H2O)3, [RhCl2(H2O)4]+, and [RhCl(H2O)5]2+ .

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