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| Name |
Sodium aluminum tetrahydride |
EINECS | 237-400-1 |
| CAS No. | 13770-96-2 | Density | 0.905 g/mL at 25ºC |
| PSA | 0.00000 | LogP | 0.45000 |
| Solubility | N/A | Melting Point |
178 ºC |
| Formula | AlH4 . Na | Boiling Point | N/A |
| Molecular Weight | 54.0031 | Flash Point | -10 ºC |
| Transport Information | UN 2835 4 | Appearance | N/A |
| Safety | Flammable when exposed to heat or flame. May ignite and explode on contact with water. Reacts violently with tetrahydrofuran when heated. When heated to decomposition it emits toxic fumes of Na2O. See also ALUMINUM COMPOUNDS and HYDRIDES. | Risk Codes | 14/15-22-34-19-15-11 |
| Molecular Structure |
|
Hazard Symbols | Severe fire and explosion risk in contact with oxidizing agents and water, forms caustic and irritating compounds. |
| Synonyms |
Aluminate(1-),tetrahydro-, sodium (8CI); Aluminate(1-), tetrahydro-, sodium, (T-4)- (9CI);Aluminum sodium hydride (AlNaH4) (6CI); Aluminum sodium tetrahydride; Sodiumaluminum hydride; Sodium aluminum hydride (NaAlH4); Sodium aluminumtetrahydride; Sodium tetrahydridoaluminate(1-); Sodium tetrahydroaluminate;Sodium tetrahydroaluminate (NaAlH4); Sodium tetrahydroaluminate(1-) |
Sodium aluminum tetrahydride Synthetic route
| Conditions | Yield |
|---|---|
| In tetrahydrofuran components solns. mixing, crystn. on abs. ether diln.; |
Sodium aluminum tetrahydride Chemical Properties
Sodium aluminium hydride is a strong reducing agent. Similar in reactivity to lithium aluminum hydride. May react violently with oxidizing agents. An explosion occurred during its preparation from sodium and aluminum in a medium of tetrahydrofuran. At elevated temperatures, the hydride reduces carbon dioxide or sodium hydrogen carbonate to methane and ethane. These gases are the explosive products formed when CO2 extinguishers have been used during hydride fires. 1:1 complexes with ether or dimethylamine and various tetrazoles are explosive. Tetrazoles include, 2-methyl, 2-ethyl, 5-ethyl, 2-methyl-5-vinyl, 5-amino-2-ethyl, etc.
IUPAC Name: Sodium alumanuide
The MF of Sodium aluminum tetrahydride (CAS NO.13770-96-2) is H4AlNa.
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The MW of Sodium aluminum tetrahydride (CAS NO.13770-96-2) is 54.0031.
Synonyms of Sodium aluminum tetrahydride (CAS NO.13770-96-2): Aluminum sodium hydride ; Sodium aluminum hydride ; Aluminate(1-), tetrahydro-, sodium (1:1)
Product Categories: Aluminum HydridesAlternative Energy;Metal Hydrides;Materials for Hydrogen Storage;Reduction;Synthetic Reagents
Apperance: white to light grey crystalline powder
Melting Point: 178 °C
Flash point: -10 °C
Density: 0.905 g/mL at 25 °C
Storage temp: water-free area
EINECS: 237-400-1
Sodium aluminum tetrahydride Uses
Sodium aluminum tetrahydride (CAS NO.13770-96-2) is used as chemical reagent, organic intermediates, fine chemicals, pharmaceutical research and development.
Sodium aluminum tetrahydride Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 9mg/kg (9mg/kg) | "Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 176, 1999. | |
| mouse | LD50 | oral | 740mg/kg (740mg/kg) | GASTROINTESTINAL: ULCERATION OR BLEEDING FROM DUODENUM GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | "Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 176, 1999. |
Sodium aluminum tetrahydride Safety Profile
Flammable when exposed to heat or flame. May ignite and explode on contact with water. Reacts violently with tetrahydrofuran when heated. When heated to decomposition it emits toxic fumes of Na2O. See also ALUMINUM COMPOUNDS and HYDRIDES.Safety information of Sodium aluminum tetrahydride (CAS NO.13770-96-2):
Hazard Codes 
F,
C
Risk Statements
14/15 Reacts violently with water, liberating extremely flammable gases
22 Harmful if swallowed
34 Causes burns
19 May form explosive peroxides
15 Contact with water liberates extremely flammable gases
11 Highly Flammable
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
43 In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
7/8 Keep container tightly closed and dry
33 Take precautionary measures against static discharges
16 Keep away from sources of ignition - No smoking
RIDADR UN 2835 4.3/PG 2
WGK Germany 1
RTECS BD0180000
F 10
HazardClass 4.3
PackingGroup II
Sodium aluminum tetrahydride Standards and Recommendations
ACGIH TLV: TWA 2 mg(Al)/m3
DOT Classification: 4.3; Label: Dangerous When Wet
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