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Basic information

  • Name:
  • Phosphine, triphenyl-,hydrobromide (1:1)

  • Superlist Name:
  • Triphenylphosphine hydrobromide
  • CAS No.:
  • 6399-81-1

  • Molecular Structure:
  • Formula:
  • C18H15P.HBr
  • Molecular Weight:
  • 343.20
  • Synonyms:
  • Phosphine,triphenyl-, compd. with hydrobromic acid (6CI,7CI);Phosphine, triphenyl-,hydrobromide (8CI,9CI);Triphenylphosphine hydrobromide;Triphenylphosphoniumbromide;
  • EINECS:
  • 229-012-6
  • Melting Point:
  • 196 °C (dec.)(lit.)
  • Boiling Point:
  • 360 °C at 760 mmHg
  • Flash Point:
  • 181.7 °C
  • Appearance:
  • white to light beige crystalline powder or chunks
  • Hazard Symbols:
  • CorrosiveC
  • Risk Codes:
  • 34
  • Safety Description:
  • 26-36/37/39-45 Details

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Chemistry

The molecular formula of Triphenylphosphine hydrobromide(6399-81-1) is C18H15PHBr and its formula weight is 343.2.
Triphenylphosphine hydrobromide(6399-81-1)  has a melting point of  196 °C (dec.)(lit.). The boiling point is  360 °C at 760 mmHg.  Its flash point is  181.7 °C.
The chemical synonyms of Triphenylphosphine hydrobromide(6399-81-1) are TPH;TRIPHENYLPHOSPHINE HYDROBROMIDE;TRIPHENYLPHOSPHONIUM BROMIDE;Triphenylphosphoniumbromide,99.9%;Phosphine, triphenyl-, hydrobromide;Triphenylphosphine hydrobromide 97%;Phosphine, triphenyl-, compd. with hydrobromic acid
The molecular structure of Triphenylphosphine hydrobromide(6399-81-1):

Toxicity Data With Reference

RTECS#: CAS# 6399-81-1: None listed
LD50/LC50: RTECS: Not available. 
Carcinogenicity: Triphenylphosphonium bromide - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated.

Safety Profile

Hazard Codes  C,Xi
Risk Statements  22-34-36/37/38
Safety Statements  26-36/37/39-45-36
RIDADR  UN 3261 8/PG 3
WGK Germany  3
Hazard Note  Corrosive
HazardClass  6.1
PackingGroup  III
HS Code  29310095

Specification

Chemical Stability: Stable under normal temperatures and pressures. 
Conditions to Avoid: Incompatible materials. 
Incompatibilities with Other Materials Strong oxidizing agents. 
Hazardous Decomposition Products Carbon monoxide, oxides of phosphorus, carbon dioxide. 
Hazardous Polymerization Has not been reported.
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