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| Name |
Tripotassium trioxalatoferrate |
EINECS | 238-954-7 |
| CAS No. | 14883-34-2 | Density | 2.13 g/cm3 |
| PSA | 188.21000 | LogP | -7.22300 |
| Solubility | N/A | Melting Point |
230 °C |
| Formula | C6FeO12K3 | Boiling Point | 365.1°C at 760 mmHg |
| Molecular Weight | 437.201 | Flash Point | 188.8°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Ferrate(3-),tris(oxalato)-, tripotassium (8CI);Ferrate(3-), tris[ethanedioato(2-)-O,O']-,tripotassium, (OC-6-11)-;Ferrate(3-), tris[ethanedioato(2-)-kO1,kO2]-, tripotassium, (OC-6-11)- (9CI);Potassiumoxalatoferrate(III) (K3[Fe(C2O4)3]) (6CI);Potassium trioxalatoferrate(III)(7CI);Iron potassium oxalate, K3Fe(C2O4)3;NSC 2915;NSC 43607;Oxalic acid,iron(3+) potassium salt (3:1:3);Potassium ferrioxalate;Potassium ironoxalate, K3Fe(C2O4)3;Potassium iron(3+) oxalate;Potassiumtris(oxalato)ferrate(III); |
Tripotassium trioxalatoferrate Chemical Properties
Molecule structure of Tripotassium trioxalatoferrate (CAS NO.14883-34-2):
Molecular Weight: 437.20 g/mol
Molecular Formula: C6FeO12K3
Appearance emerald green hydrated crystals
Density: 2.13 g/cm3
Melting Point: 230 °C
EINECS: 238-954-7
Tripotassium trioxalatoferrate Uses
Tripotassium trioxalatoferrate (CAS NO.14883-34-2) is often used in chemical actinometry.
Tripotassium trioxalatoferrate Production
The Tripotassium trioxalatoferrate can be made from the reaction between potassium oxalate, iron(III) sulfate and barium oxalate :
Fe2(SO4)3 + 3 Ba(C2O4) + 3 K2(C2O4) → 2 K3[Fe(C2O4)3] + 3 BaSO4
The reactants are dissolved in water and heated for about 1.5 hours. BaSO4 precipitates out leaving behind the newly formed complex in solution. The complex can then be got by filtering off the BaSO4 and cooling the solution so that it crystallizes out.
Tripotassium trioxalatoferrate Safety Profile
RIDADR: 3288
HazardClass: 6.1(b)
PackingGroup: III
Tripotassium trioxalatoferrate Specification
Tripotassium trioxalatoferrate (CAS NO.14883-34-2) is also named as Kalium-Eisen(III)-oxalat-3-hydrat ; PotassiumIron(III)oxalatetrihydrate . In solution, the Tripotassium trioxalatoferrate dissociates to give the ferrioxalate anion, [Fe(C2O4)3]3-, which appears fluorescent green in color.
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