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Cas Database |
| Name |
Tropane |
EINECS | N/A |
| CAS No. | 529-17-9 | Density | 0.934g/cm3 |
| PSA | 3.24000 | LogP | 1.57100 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C8H15 N | Boiling Point | 166°Cat760mmHg |
| Molecular Weight | 125.214 | Flash Point | 42.2°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | R10; R36/37/38 | |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Tropane(6CI,7CI,8CI); 1aH,5aH-Tropane;2,3-Dihydro-8-methylnortropidine; 8-Methyl-8-azabicyclo[3.2.1]octane;N-Methyl-8-azabicyclo[3.2.1]octane |
Article Data | 27 |
Tropane Synthetic route
| Conditions | Yield |
|---|---|
| With hydrogenchloride; hydrogen; platinum(IV) oxide under 1.5 Torr; for 35h; | 100% |
| With potassium hydroxide; hydrazine In 2,2'-[1,2-ethanediylbis(oxy)]bisethanol for 8h; Wolff-Kischener reduction; Heating; |
- 201230-82-2
carbon monoxide
- 529-18-0
tropidine
A
- 529-17-9
tropane
B
- 68969-37-9
tropan-2-yl-methanol
C
- 90949-82-9, 888716-28-7
3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane
D
- 93047-52-0, 99658-61-4
Tropan-3β-carboxaldehyd
| Conditions | Yield |
|---|---|
| With hydrogen; di-μ-chlorobis(norbornadiene)dirhodium(I); tributylphosphine In benzene at 100℃; under 60004.8 Torr; for 6h; | A 2% B n/a C n/a D 92% |
- 201230-82-2
carbon monoxide
- 529-18-0
tropidine
A
- 529-17-9
tropane
B
- 68969-37-9
tropan-2-yl-methanol
C
- 90949-82-9, 888716-28-7
3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane
D
- 93047-52-0, 99658-61-4
Tropan-3β-carboxaldehyd
| Conditions | Yield |
|---|---|
| With hydrogen; carbonylhydridetris(triphenylphosphine)rhodium(I) In benzene at 100℃; under 60004.8 Torr; for 6h; Product distribution; various catalysts, formed in situ from various phosphines; | A 2% B n/a C n/a D 86% E 10% |
- 95799-01-2
N-<(benzoyloxy)carbonyl>nortropane
- 529-17-9
tropane
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In tetrahydrofuran for 24h; Ambient temperature; | 72% |
- 122709-62-0
1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione
A
- 529-17-9
tropane
B
- 128729-93-1
2-(2-pyridylthio)tropane
| Conditions | Yield |
|---|---|
| With 2-methylpropan-2-thiol; acetic acid In acetonitrile at 25℃; Irradiation; | A 68% B 3 % Chromat. |
- 201230-82-2
carbon monoxide
- 529-18-0
tropidine
A
- 529-17-9
tropane
B
- 93047-52-0, 99658-61-4
Tropan-3β-carboxaldehyd
| Conditions | Yield |
|---|---|
| With hydrogen; di-μ-chlorobis(norbornadiene)dirhodium(I); tricyclohexylphosphine In benzene at 100℃; under 60004.8 Torr; for 6h; | A 22% B 67% C 11% |
- 122709-62-0
1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione
- 529-17-9
tropane
| Conditions | Yield |
|---|---|
| With 2-methylpropan-2-thiol; acetic acid In benzene at 4℃; | 67% |
- 42870-65-5
N-methyl-N-cycloheptylamine
- 529-17-9
tropane
| Conditions | Yield |
|---|---|
| With chlorine Erwaermen des erhaltenen Chlor-cycloheptyl-methyl-amins mit 84%ig. wss. Schwefelsaeure; |
- 529-18-0, 122709-67-5
Tropidin
- 529-17-9
tropane
| Conditions | Yield |
|---|---|
| With diethyl ether; platinum Hydrogenation; |
| Conditions | Yield |
|---|---|
| With phosphonium iodide; hydrogen iodide at 195 - 200℃; im Rohr; |
Tropane Chemical Properties
Molecular Structure of Tropane (CAS NO. 529-17-9):
.jpg)
IUPAC Name: 8-Methyl-8-azabicyclo[3.2.1]octane
Molecular Formula: 125.211400 g/mol
Molecular Weight: C8H15N
Index of Refraction: 1.488
Molar Refractivity: 38.6 cm3
Molar Volume: 134 cm3
Surface Tension: 29.9 dyne/cm
Density: 0.934 g/cm3
Flash Point: 42.2 °C
Enthalpy of Vaporization: 40.25 kJ/mol
Boiling Point: 166 °C at 760 mmHg
Vapour Pressure: 1.82 mmHg at 25 °C
Refractive Index: n20/D 1.477(lit.)
Product Categories: Heterocyclic Compounds
Tropane Safety Profile
Safety Information of Tropane (CAS NO. 529-17-9):
Hazard Codes: Xi 
Risk Statements: 10-36/37/38
R10: Flammable
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 16-26-36
S16: Keep away from sources of ignition
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36: Wear suitable protective clothing
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
HazardClass: 3.2
PackingGroup: III
Tropane Specification
Tropane with cas registry number of 529-17-9 is a nitrogenous bicyclic organic compound. It is mainly known for a group of alkaloids derived from it, which include atropine and cocaine. Both alkaloids contain tropinone from which tropane is a derivate. Tropane alkaloids occur in plants of the families Erythroxylaceae (including coca) and Solanaceae (including mandrake, henbane, deadly nightshade, datura, potato, tomato). Tropane is also known as 8-Azabicyclo(3.2.1)octane, 8-methyl- .
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