Products Categories
CAS No.: | 1000623-98-2 |
---|---|
Name: | 2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole |
Article Data: | 7 |
Molecular Structure: | |
Formula: | C46H70Br2N2O2S2 |
Molecular Weight: | 907.014 |
Synonyms: | 2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole;3,6-Bis(5-broMo-2-thienyl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione;3,6-bis(5-broMo-2-thienyl)-2,5-bis(2-hexyldecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione DPP-iC16;Pyrrolo[3,4-c]pyrrole-1,4-dione,3,6-bis(5-bromo-2-thienyl)-2-5-bis(2-hexyldecyl)-2,5-dihydro-;3,6-bis(5-bromothiophen-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione;3,6-Bis(5-bromo-2-thienyl)-2,5-bis(2-hexyldecyl)-2,5-dihydro-pyrrolo[3,4-c]pyrrole-1,4-dione 98% |
EINECS: | -0 |
Density: | 1.24±0.1 g/cm3(Predicted) |
Melting Point: | 110-115°C |
Boiling Point: | 865.4±65.0 °C(Predicted) |
PSA: | 100.48000 |
LogP: | 16.20900 |
3,6-bis(5-bromothien-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
Conditions | Yield |
---|---|
With N-Bromosuccinimide In chloroform at 50℃; for 2h; Inert atmosphere; | 79.9% |
With N-Bromosuccinimide In chloroform for 48h; Darkness; | 61% |
With N-Bromosuccinimide In chloroform for 48h; Darkness; | 60% |
3,6-bis(5-bromothien-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
A
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
B
3-(5-bromothiophen-2-yl)-2,5-bis(2-hexyldecyl)-6-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
Conditions | Yield |
---|---|
With N-Bromosuccinimide In chloroform at 0 - 20℃; Darkness; | A 17% B 56% |
7-(iodomethyl)pentadecane
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: potassium carbonate / N,N-dimethyl-formamide / 120 °C 2: N-Bromosuccinimide / chloroform / 20 °C View Scheme |
thiophene-2-carbonitrile
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: sodium / tert-Amyl alcohol / 120 °C 2: potassium carbonate / N,N-dimethyl-formamide / 120 °C 3: N-Bromosuccinimide / chloroform / 20 °C View Scheme | |
Multi-step reaction with 3 steps 1: potassium tert-butylate / tert-Amyl alcohol / 4 h / 110 °C 2: potassium carbonate / N,N-dimethyl-formamide / 24 h / 110 °C 3: N-Bromosuccinimide / chloroform / 48 h / Darkness View Scheme | |
Multi-step reaction with 3 steps 1.1: potassium tert-butylate / tert-Amyl alcohol / 5 h / 110 °C / Inert atmosphere 2.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 130 °C / Inert atmosphere 2.2: 130 °C / Inert atmosphere 3.1: N-Bromosuccinimide / chloroform / 2 h / 50 °C / Inert atmosphere View Scheme |
2-hexyldecan-1-ol
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 20 °C 2: potassium carbonate / N,N-dimethyl-formamide / 120 °C 3: N-Bromosuccinimide / chloroform / 20 °C View Scheme |
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 110 °C 2: N-Bromosuccinimide / chloroform / 48 h / Darkness View Scheme |
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
Conditions | Yield |
---|---|
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione; 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole With tris-(dibenzylideneacetone)dipalladium(0); Aliquat (at)366; triphenylphosphine In water; toluene for 0.25h; Schlenk technique; Inert atmosphere; Stage #2: With potassium phosphate In water; toluene at 115℃; for 16h; Schlenk technique; Inert atmosphere; Sealed tube; | 97% |
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
Conditions | Yield |
---|---|
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione; 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole With tris-(dibenzylideneacetone)dipalladium(0); Aliquat (at)366; triphenylphosphine In water; toluene Schlenk technique; Inert atmosphere; Stage #2: With potassium phosphate In water; toluene at 115℃; Schlenk technique; Inert atmosphere; Sealed tube; | A 87% B 6.6% |
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
2-Ethynylanthracene
Conditions | Yield |
---|---|
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine In toluene at 60℃; for 8h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique; | 75% |
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
C15H15BF2N2
Conditions | Yield |
---|---|
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine In tetrahydrofuran Schlenk technique; Inert atmosphere; Stage #2: C15H15BF2N2 In tetrahydrofuran at 60℃; for 3h; Inert atmosphere; | 75% |