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CAS No.: | 1002-94-4 |
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Name: | (10Z,12E)-10,12-Hexadecadien-1-ol |
Article Data: | 8 |
Molecular Structure: | |
Formula: | C16H30 O |
Molecular Weight: | 238.414 |
Synonyms: | 10,12-Hexadecadien-1-ol,(E,Z)- (8CI); Hexadeca-10-cis,12-trans-dien-1-ol; Isobombycol; Isobombykol |
Density: | 0.859g/cm3 |
Boiling Point: | 298.3°Cat760mmHg |
Flash Point: | 133.5°C |
PSA: | 20.23000 |
LogP: | 5.01200 |
(E)-pent-1-en-1-yl-1,3,2-benzodioxaborole
(Z)-11-hydroxy-1-undecenyl bromide
(10Z,12E)-hexadecadien-1-ol
Conditions | Yield |
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With tetrakis(triphenylphosphine) palladium(0); sodium ethanolate In ethanol; benzene for 2.5h; Heating; | 77% |
ω-(Ethoxycarbonyl)nonanal
<(E)-hex-2-enyl>triphenylphosphonium bromide
(10Z,12E)-hexadecadien-1-ol
Conditions | Yield |
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(i) NaOEt, EtOH, (ii) LiAlH4; Multistep reaction; |
ω-(Ethoxycarbonyl)nonanal
<(E)-hex-2-enyl>triphenylphosphonium bromide
A
(10Z,12E)-hexadecadien-1-ol
B
(10E,12E)-hexadeca-10,12-dien-1-ol
Conditions | Yield |
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(i) NaOEt, EtOH, (ii) LiAlH4; Multistep reaction; |
Conditions | Yield |
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With quinoline; hydrogen; Lindlar's catalyst |
Conditions | Yield |
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With lithium aluminium tetrahydride In diethyl ether |
Conditions | Yield |
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With benzo[1,3,2]dioxaborole; tetrakis(triphenylphosphine) palladium(0) Yield given. Multistep reaction; |
(E)-(11-hydroxy-1-undecenyl)boronic acid
(10Z,12E)-hexadecadien-1-ol
Conditions | Yield |
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Multi-step reaction with 2 steps 1: 1.) Br2; 2.) NaOEt / 1.) CHCl3, CCl4, -10 to 0 deg C, 1 h; 2.) CHCl3, CCl4, ethanol, 30 min 2: 77 percent / Pd(PPh3)4/NaOEt / benzene; ethanol / 2.5 h / Heating View Scheme |
Conditions | Yield |
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Multi-step reaction with 3 steps 1: 1) 1,3,2-benzodioxaborole, then hydrolysis; 2) bromine 2: NaOMe 3: 1) 1,3,2-benzodioxaborole / 2) Pd(PPh3)4 View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: Br2 / -10 - 0 °C 2: NaOMe 3: 1) 1,3,2-benzodioxaborole / 2) Pd(PPh3)4 View Scheme |
Conditions | Yield |
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Multi-step reaction with 4 steps 1: LiAlH4 2: Br2 / -10 - 0 °C 3: NaOMe 4: 1) 1,3,2-benzodioxaborole / 2) Pd(PPh3)4 View Scheme |