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1002-94-4

Basic Information
CAS No.: 1002-94-4
Name: (10Z,12E)-10,12-Hexadecadien-1-ol
Article Data: 8
Molecular Structure:
Molecular Structure of 1002-94-4 ((10Z,12E)-10,12-Hexadecadien-1-ol)
Formula: C16H30 O
Molecular Weight: 238.414
Synonyms: 10,12-Hexadecadien-1-ol,(E,Z)- (8CI); Hexadeca-10-cis,12-trans-dien-1-ol; Isobombycol; Isobombykol
Density: 0.859g/cm3
Boiling Point: 298.3°Cat760mmHg
Flash Point: 133.5°C
PSA: 20.23000
LogP: 5.01200
Synthetic route
37494-02-3

(E)-pent-1-en-1-yl-1,3,2-benzodioxaborole

87096-21-7

(Z)-11-hydroxy-1-undecenyl bromide

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium ethanolate In ethanol; benzene for 2.5h; Heating;77%
692-87-5

ω-(Ethoxycarbonyl)nonanal

88517-93-5

<(E)-hex-2-enyl>triphenylphosphonium bromide

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
(i) NaOEt, EtOH, (ii) LiAlH4; Multistep reaction;
692-87-5

ω-(Ethoxycarbonyl)nonanal

88517-93-5

<(E)-hex-2-enyl>triphenylphosphonium bromide

A

1002-94-4

(10Z,12E)-hexadecadien-1-ol

B

765-19-5

(10E,12E)-hexadeca-10,12-dien-1-ol

Conditions
ConditionsYield
(i) NaOEt, EtOH, (ii) LiAlH4; Multistep reaction;
765-23-1

hexadec-12t-en-10-yn-1-ol

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
With quinoline; hydrogen; Lindlar's catalyst
929-66-8

hexadeca-10c,12t-dienoic acid methyl ester

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether
627-19-0

1-Pentyne

87096-21-7

(Z)-11-hydroxy-1-undecenyl bromide

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
With benzo[1,3,2]dioxaborole; tetrakis(triphenylphosphine) palladium(0) Yield given. Multistep reaction;
87096-18-2

(E)-(11-hydroxy-1-undecenyl)boronic acid

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) Br2; 2.) NaOEt / 1.) CHCl3, CCl4, -10 to 0 deg C, 1 h; 2.) CHCl3, CCl4, ethanol, 30 min
2: 77 percent / Pd(PPh3)4/NaOEt / benzene; ethanol / 2.5 h / Heating
View Scheme
2774-84-7

undec-10-yn-1-ol

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1) 1,3,2-benzodioxaborole, then hydrolysis; 2) bromine
2: NaOMe
3: 1) 1,3,2-benzodioxaborole / 2) Pd(PPh3)4
View Scheme
112-43-6

10-Undecen-1-ol

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: Br2 / -10 - 0 °C
2: NaOMe
3: 1) 1,3,2-benzodioxaborole / 2) Pd(PPh3)4
View Scheme
111-81-9

Methyl 10-undecenoate

1002-94-4

(10Z,12E)-hexadecadien-1-ol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: LiAlH4
2: Br2 / -10 - 0 °C
3: NaOMe
4: 1) 1,3,2-benzodioxaborole / 2) Pd(PPh3)4
View Scheme
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