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CAS No.: | 10060-11-4 | ||||||||||||
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Name: | GERMANIUM DICHLORIDE-DIOXANE COMPLEX | ||||||||||||
Article Data: | 4 | ||||||||||||
Molecular Structure: | |||||||||||||
Formula: | Cl2Ge | ||||||||||||
Molecular Weight: | 143.496 | ||||||||||||
Synonyms: | Dichlorogermylene;Germanium dichloride; Germanium(2+) chloride | ||||||||||||
Density: | g/cm3 | ||||||||||||
Melting Point: | 110-165°C (dec.) | ||||||||||||
Boiling Point: | °Cat760mmHg | ||||||||||||
Flash Point: | °C | ||||||||||||
Solubility: | decomposes in H2O; soluble ether, benzene; insolublealcohol and chloroform [HAW93] [MER06] | ||||||||||||
Risk Codes: | 34 | ||||||||||||
Safety: |
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PSA: | 18.46000 | ||||||||||||
LogP: | 1.25640 |
diazoacetic acid ethyl ester
Triethylgerman
germaniumtetrachloride
phenylmagnesium bromide
A
germanium dichloride
B
triethyl(phenyl)germane
C
tetraphenylgermane
Conditions | Yield |
---|---|
In pentane byproducts: N2; 1 equiv of diazoester adding to a soln. of equimolar mixt. of Ge derivs., allowing to stand for 48 h at 20°C, orange-red oil decanting, PhMgBr adding to a supernatant; identified as adduct with ClCH2OMe; | A 57% B n/a C n/a |
germanium
Iodine monochloride
A
germanium monochloride
B
germanium dichloride
Conditions | Yield |
---|---|
In gas Kinetics; metals were vaporized in a high temperature beam and the vapor were collimated upon entering a separatly pumped chamber filled with halogen; chemiluminescence spectroscopy; |
Conditions | Yield |
---|---|
excess of GeS; |
Conditions | Yield |
---|---|
350-400°C; |
Conditions | Yield |
---|---|
In neat (no solvent, gas phase) at 550°C; detn. by chemical trapping; |
germanium hydride trichloride
germanium dichloride
Conditions | Yield |
---|---|
byproducts: HCl; thermal decompn.; |