Products Categories
CAS No.: | 101372-99-0 |
---|---|
Name: | 4,6,10-Hexadecatrien-1-ol, acetate, (E,E,Z)- |
Article Data: | 2 |
Molecular Structure: | |
Formula: | C18H30O2 |
Molecular Weight: | 278.435 |
Synonyms: | (E,E,Z)-4,6,10-hexadecatrienyl acetate;(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate;4,6,10-Hexadecatrien-1-ol,acetate,(E,E,Z); |
PSA: | 57.53000 |
LogP: | 4.87890 |
(4E,6E,10Z)-hexadeca-4,6,10-trien-1-ol
acetic anhydride
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
With pyridine at 20℃; Concentration; Inert atmosphere; | 97% |
acetic anhydride
(E,Z)-4,6,10-hexadecatrienyl alcohol
A
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
B
(4E,6Z,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
With pyridine Ambient temperature; Yield given. Yields of byproduct given; |
(Z)-4-decenal
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 1.) n-BuLi / 1.) THF, hexane, 0 deg C, 1 h, 2.) THF, hexane, RT, 30 min 2: PPTs / methanol / 24 h / Ambient temperature 3: pyridine / Ambient temperature View Scheme |
1-<(tetrahydropyranyl)oxy>-(4E,10Z)-hexadecatriene
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: PPTs / methanol / 24 h / Ambient temperature 2: pyridine / Ambient temperature View Scheme |
(Z)-4-decenyltriphenylphosphonium bromide
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 1.) t-BuOK / 1.) THF, -30 deg C, 30 min, 2.) THF, 2 h 2: PPTs / methanol / 24 h / Ambient temperature 3: pyridine / Ambient temperature View Scheme |
6-<(tetrahydropyranyl)oxy>-2E-hexanetriphenylphosphonium bromide
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 1.) n-BuLi / 1.) THF, hexane, 0 deg C, 1 h, 2.) THF, hexane, RT, 30 min 2: PPTs / methanol / 24 h / Ambient temperature 3: pyridine / Ambient temperature View Scheme |
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: toluene-4-sulfonic acid / methanol / 20 °C 2: lithium; ammonium hydroxide 3: pyridine / 20 °C / Inert atmosphere View Scheme |
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: lithium; ammonium hydroxide 2: pyridine / 20 °C / Inert atmosphere View Scheme |
pent-1-yn-5-ol
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1.1: toluene-4-sulfonic acid / dichloromethane / 0 °C / Inert atmosphere 2.1: tetrakis(triphenylphosphine) palladium(0); copper(l) iodide; diisopropylamine / tetrahydrofuran / 8 h / 20 °C / Inert atmosphere 3.1: iron(III)-acetylacetonate; 1-methyl-pyrrolidin-2-one / tetrahydrofuran / -20 - -15 °C / Inert atmosphere 3.2: 8 h / -15 - 20 °C / Inert atmosphere 4.1: toluene-4-sulfonic acid / methanol / 20 °C 5.1: lithium; ammonium hydroxide 6.1: pyridine / 20 °C / Inert atmosphere View Scheme |
1-(tetrahydropyranyloxy)-4-pentyn
(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: tetrakis(triphenylphosphine) palladium(0); copper(l) iodide; diisopropylamine / tetrahydrofuran / 8 h / 20 °C / Inert atmosphere 2.1: iron(III)-acetylacetonate; 1-methyl-pyrrolidin-2-one / tetrahydrofuran / -20 - -15 °C / Inert atmosphere 2.2: 8 h / -15 - 20 °C / Inert atmosphere 3.1: toluene-4-sulfonic acid / methanol / 20 °C 4.1: lithium; ammonium hydroxide 5.1: pyridine / 20 °C / Inert atmosphere View Scheme |