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| CAS No.: | 10196-18-6 |
|---|---|
| Name: | Zinc nitrate hexahydrate |
| Article Data: | 68 |
| Molecular Structure: | |
|
|
|
| Formula: | Zn(NO3)2.6(H2O) |
| Molecular Weight: | 189.4 |
| Synonyms: | Nitricacid, zinc salt, hexahydrate (8CI,9CI);Nitric acid, zinc salt,hydrate (2:1:6);Zincnitrate (Zn(NO3)2), hexahydrate;Zinc nitratehexahydrate (Zn(NO3)2.6H2O); |
| EINECS: | 231-943-8 |
| Density: | 2.065 g/mL at 25 °C(lit.) |
| Melting Point: | 36 °C(lit.) |
| Boiling Point: | 105～131oC (-6H2O) |
| Solubility: | 1800 g/L (20 °C) in water |
| Appearance: | white crystal |
| Hazard Symbols: |
 O,  Xn
|
| Risk Codes: | 8-22-36/37/38-38 |
| Safety: | 17-26-24/25 |
| Transport Information: | UN 1514 5.1/PG 2 |
| PSA: | 193.14000 |
| LogP: | 0.17990 |
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- 10196-18-6
zinc(II) nitrate
| Conditions | Yield |
|---|---|
| at 20 - 800℃; | 69.8% |
- 7440-66-6
zinc
A
- 10196-18-6
zinc(II) nitrate
| Conditions | Yield |
|---|---|
| In water aq. soln. of Al(NO3)3*9H2O treated with Zn, stirred overnight; filtered, evapd., washed with isopropanol; monitored by XRD; | A n/a B 55.2% |
| Conditions | Yield |
|---|---|
| In nitric acid prepn. by treating of metal carbonate with 70% HNO3 at room temp.; washed (petroleum ether); recrystd. (H2O); dried over fused CaCl2 in desiccator; |
| Conditions | Yield |
|---|---|
| In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;; | |
| In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;; |
- 10196-18-6
zinc(II) nitrate
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;; | 0% |
| In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;; | 0% |
| Conditions | Yield |
|---|---|
| In nitric acid aq. HNO3; oxide dissoln. soln. evapn. to dryness; residue dissoln. in water, soln. evapn. (excess acid removal); | |
| In water | |
| In water |
| Conditions | Yield |
|---|---|
| In further solvent(s) byproducts: NH3, H2O; on dissolving of ZnO in molten ammonium nitrate;; | |
| byproducts: NH3; H2O; |
| Conditions | Yield |
|---|---|
| In water Irradiation (UV/VIS); addition of solid ZnO to a solution of AgNO3 in H2O; sun light (day light) irradiation;; |
| Conditions | Yield |
|---|---|
| byproducts: Ag, O2; Irradiation (UV/VIS); irradiated ZnO is reacting with AgNO3;; |
| Conditions | Yield |
|---|---|
| on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;; | |
| on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;; |
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This product is a nationally controlled contraband, and the Lookchem platform doesn't provide relevant sales information.
Chemistry
Molecule structure of Zinc nitrate hexahydrate (CAS NO.10196-18-6):
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IUPAC Name: Zinc dinitrate hexahydrate
Molecular Weight: 297.51048 g/mol
Molecular Formula: H12N2O12Zn
Density: 2.065 g/mL at 25 °C(lit.)
Melting Point: 36 °C(lit.)
Water Solubility: 1800 G/L (20 °C)
H-Bond Donor: 6
H-Bond Acceptor: 12
Exact Mass: 295.96817
MonoIsotopic Mass: 295.96817
Topological Polar Surface Area: 138
Heavy Atom Count: 15
Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Zn+2]
InChI: InChI=1S/2NO3.6H2O.Zn/c2*2-1(3)4;;;;;;;/h;;6*1H2;/q2*-1;;;;;;;+2
InChIKey: JGPSMWXKRPZZRG-UHFFFAOYSA-N
EINECS: 231-943-8
Product Categories: Essential Chemicals; Reagent Grade; Routine Reagents
Uses
Zinc nitrate hexahydrate (CAS NO.10196-18-6) is mainly used for machines and bicycle parts galvanized, preparation of steel phosphating agent. It is also used as a mordant in dyeing. And it's used as analytical reagent, but also for the pharmaceutical industry.
Production
The following is the reaction fomular of preparation of Zinc nitrate hexahydrate .
ZnO +2 HNO3 → Zn (NO3) 2 + H2O
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 110mg/kg (110mg/kg) | SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
| mouse | LD50 | oral | 926mg/kg (926mg/kg) | SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
| rat | LD50 | intraperitoneal | 133mg/kg (133mg/kg) | SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
| rat | LD50 | oral | 1190mg/kg (1190mg/kg) | "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 10, 1972. |
Consensus Reports
Zinc and its compounds are on the Community Right-To-Know List.
Safety Profile
Hazard Codes: 
O, 
Xn
Risk Statements: 8-22-36/37/38-38
R8 :Contact with combustible material may cause fire.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R38:Irritating to skin.
Safety Statements: 17-26-24/25
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 1514 5.1/PG 2
WGK Germany: 3
RTECS: ZH4775000
HazardClass: 5.1
PackingGroup: II
Moderately toxic by ingestion. A severe skin and eye irritant. Can react violently with carbon; copper; metal sulfides; organic matter; phosphorus; sulfur. When heated to decomposition it emits toxic fumes of NOx and ZnO. See also ZINC COMPOUNDS and NITRATES.
Specification
Zinc nitrate hexahydrate (CAS NO.10196-18-6) is also named as CCRIS 8894 ; Dusicnan zinecnaty ; Dusicnan zinecnaty [Czech] ; Nitric acid, zinc salt, hexahydrate ; Zinc(II) nitrate, hexahydrate (1:2:6) . Zinc nitrate hexahydrate (CAS NO.10196-18-6) is white crystal. It is soluble in water and ethanol .