CAS No.10508-09-5,Bis(1,1-dimethylpropyl) peroxide Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	10508-09-5
Name:	Bis(1,1-dimethylpropyl) peroxide
Article Data:	10

Formula:	C₁₀H₂₂O₂
Molecular Weight:	174.283
Synonyms:	tert-Pentylperoxide (6CI,7CI,8CI);Di-t-amyl peroxide;Di-tert-amyl peroxide;Luperox DTA;Peroximon S 172;Trigonox 201;tert-Amyl peroxide;
EINECS:	234-042-8
Density:	0.844 g/cm³
Melting Point:	-55oC
Boiling Point:	177.708 °C at 760 mmHg
Flash Point:	41.092 °C
Solubility:	13.83mg/L at 20℃
Appearance:	COA
Hazard Symbols:	O,Xn
Risk Codes:	8-22-38-7
Safety:	7-16-17-36/37/39-47-14
Transport Information:	UN 3107 5.2
PSA:	18.46000
LogP:	3.31180

Synthetic route

: 75-85-4
tert-Amyl alcohol

: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
Stage #1: tert-Amyl alcohol With sulfuric acid at 0℃; for 4h; Inert atmosphere; Stage #2: With sulfuric acid; dihydrogen peroxide at 0℃; Inert atmosphere;	43%
With sulfuric acid; dihydrogen peroxide

: 75-85-4
tert-Amyl alcohol

: 3425-61-4
tert-amyl hydroperoxide

: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
With sulfuric acid

: 78-78-4
methylbutane

: 110-05-4
di-tert-butyl peroxide

: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
at 150℃; under 20594.2 Torr; Leiten von Luft;und Behandeln des Reaktionsprodukts mit tert-Pentylalkohol und 60prozentig.wss.Schwefelsaeure;

: 78-78-4
methylbutane

: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
With hydrogen bromide; oxygen at 165℃;

: 123-51-3
i-Amyl alcohol

: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
(i) Al2O3, (heating), (ii) aq. H2SO4, (iii) aq. H2O2; Multistep reaction;

: 507-36-8
2-bromo-2-methylbutane

: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
With dihydrogen peroxide; silver trifluoroacetate

tert-pentylsulfuric acid: tert-pentylsulfuric acid

: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
With sulfuric acid; dihydrogen peroxide at 5℃;

: 78-78-4
methylbutane

: 10035-10-6, 12258-64-9
hydrogen bromide

A: 75-85-4
tert-Amyl alcohol

B: 3425-61-4
tert-amyl hydroperoxide

C: 10508-09-5
di-tert-amyl peroxide

Conditions

Conditions	Yield
at 165℃; Bei der Oxydation;

...Expand

: 75-85-4
tert-Amyl alcohol

A: 3425-61-4
tert-amyl hydroperoxide

B: 10508-09-5
di-tert-amyl peroxide

C: 1642887-92-0
tert-amyl hydrogen peroxysulfate

D: 67-64-1
acetone

Conditions

Conditions	Yield
With sulfuric acid; dihydrogen peroxide In water at 24.84℃; for 2h; pH=1; Kinetics;

...Expand

: 10508-09-5
di-tert-amyl peroxide

: 22731-83-5
S,S-diphenylsulphoximine

: 62129-79-7
N-ethyl diphenyl sulfoximine

Conditions

Conditions	Yield
With copper diacetate In dimethyl sulfoxide at 110℃; for 16h; Inert atmosphere; Schlenk technique;	81%

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Specification

The Bis(1,1-dimethylpropyl) peroxide with its cas register number is 10508-09-5. It also can be called as Peroxide, bis(1,1-dimethylpropyl) and the IUPAC name about this chemical is 2-methyl-2-(2-methylbutan-2-ylperoxy)butane.

Physical properties about Bis(1,1-dimethylpropyl) peroxide are: (1)ACD/LogP: 4.26; (2)ACD/LogD (pH 5.5): 4.26; (3)ACD/LogD (pH 7.4): 4.26; (4)ACD/BCF (pH 5.5): 1011.03; (5)ACD/BCF (pH 7.4): 1011.03; (6)ACD/KOC (pH 5.5): 4925.04; (7)ACD/KOC (pH 7.4): 4925.04; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 5; (10)Polar Surface Area: 18.46Å²; (11)Index of Refraction: 1.415; (12)Molar Refractivity: 51.79 cm³; (13)Molar Volume: 206.4 cm³; (14)Polarizability: 20.53x10^-24cm³; (15)Surface Tension: 24.5 dyne/cm; (16)Enthalpy of Vaporization: 39.7 kJ/mol; (17)Vapour Pressure: 1.38 mmHg at 25°C

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating skin and it is harmful if swallowed, contact with combustible material may cause fire, also it may cause fire. When you are using it, wear suitable protective clothing, gloves and eye/face protection, keep away from sources of ignition and keep away from combustible material. If you want to store this chemical, please keep container tightly closed and keep at temperature not exceeding...

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CCC(C)(C)OOC(C)(C)CC
(2)InChI: InChI=1S/C10H22O2/c1-7-9(3,4)11-12-10(5,6)8-2/h7-8H2,1-6H3
(3)InChIKey: JJRDRFZYKKFYMO-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	oral	1450mg/kg (1450mg/kg)		"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 263, 1986.