Products Categories
CAS No.: | 1060735-14-9 |
---|---|
Name: | 9-Phenyl-9H,9'H-[3,3']bicarbazolyl |
Article Data: | 65 |
Molecular Structure: | |
Formula: | C30H20N2 |
Molecular Weight: | 408.502 |
Synonyms: | .3-(9-phenyl-9H-carbazol-3-yl)-9H-carbazole;9-PHENYL-9H,9'H-[3,3']BICARBAZOLYL;.PCC;9-phenyl-9H,9'H-3,3'-bicarbazole;.9-phenyl-9H,9'H-[3,3']bicarbazolyl;.9-phenyl-3,3'-bi(9H-carbazol);.9-phenyl-3,3'-bi(9H-carbazole); |
EINECS: | 1312995-182-4 |
Density: | 1.23±0.1 g/cm3(Predicted) |
Boiling Point: | 685.6±37.0 °C(Predicted) |
PSA: | 20.72000 |
LogP: | 8.08520 |
N-phenyl-9H-carbazol-3-boronic acid
3-bromo-9H-carbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
Stage #1: N-phenyl-9H-carbazol-3-boronic acid; 3-bromo-9H-carbazole With potassium carbonate In ethanol; water; toluene for 0.5h; Inert atmosphere; Stage #2: With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine In ethanol; water; toluene for 2h; Reflux; | 97% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene for 12h; Inert atmosphere; Reflux; | 90% |
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium carbonate In 1,4-dioxane; water for 4h; Inert atmosphere; Reflux; | 86% |
3-bromo-9-phenyl-9H-carbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene for 12h; Reflux; | 90% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran at 65℃; for 18h; | 73% |
3-bromo-9H-carbazole
9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In water; toluene for 5h; Inert atmosphere; Reflux; | 87% |
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In 1,4-dioxane for 4h; Inert atmosphere; Reflux; | 80% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 24h; Inert atmosphere; | 77% |
N-phenyl-9H-carbazol-3-boronic acid
3-iodocarbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene at 80℃; for 7h; Inert atmosphere; | 84% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene at 80℃; for 7h; Inert atmosphere; | 2.43 g |
3-bromo-9-phenyl-9H-carbazole
3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; sodium hydroxide In water; toluene at 80℃; for 12h; Inert atmosphere; | 75% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene for 12h; Reflux; | 61% |
3-iodocarbazole
9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 85℃; for 48h; Inert atmosphere; | 74% |
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 85℃; for 48h; Suzuki coupling; Inert atmosphere; | 74% |
9H-carbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
With N-Bromosuccinimide In methanol; (2S)-N-methyl-1-phenylpropan-2-amine hydrate; 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; N,N-dimethyl-formamide | |
Multi-step reaction with 4 steps 1: potassium carbonate; 18-crown-6 ether; tri-tert-butyl phosphine / tris-(dibenzylideneacetone)dipalladium(0) / toluene; xylene / 18 h / Inert atmosphere; Reflux 2: N-Bromosuccinimide / N,N-dimethyl-formamide / 0 °C 3: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 6 h / 80 °C / Inert atmosphere 4: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 5 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 2 steps 1: N-Bromosuccinimide / N,N-dimethyl-formamide / 0 °C 2: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 5 h / Inert atmosphere; Reflux View Scheme |
bromobenzene
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: potassium carbonate; 18-crown-6 ether; tri-tert-butyl phosphine / tris-(dibenzylideneacetone)dipalladium(0) / toluene; xylene / 18 h / Inert atmosphere; Reflux 2: N-Bromosuccinimide / N,N-dimethyl-formamide / 0 °C 3: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 6 h / 80 °C / Inert atmosphere 4: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 5 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 2 steps 1: potassium acetate; dibenzo-18-crown-6; copper / N,N-dimethyl-formamide / 4 h / 120 °C 2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 18 h / 65 °C View Scheme |
3-bromo-9-phenyl-9H-carbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 6 h / 80 °C / Inert atmosphere 2: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 5 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 2 steps 1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C 1.2: 8 h / 20 °C 2.1: potassium phosphate / tetrakis(triphenylphosphine) palladium(0) / 1,4-dioxane / 48 h / 85 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C 1.2: 12 h / 20 °C 2.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; ethanol / 5 h / Reflux View Scheme | |
Multi-step reaction with 2 steps 1.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C 1.2: -78 - 20 °C 2.1: tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 80 - 90 °C / Alkaline conditions View Scheme | |
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere 1.2: -78 °C / Inert atmosphere 1.3: 0.5 h / Inert atmosphere 2.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 8 h / Reflux; Inert atmosphere View Scheme |
N-phenylcarbazole
9-phenyl-3,3'-bicarbazole
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: N-Bromosuccinimide / N,N-dimethyl-formamide / 0 °C 2: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 6 h / 80 °C / Inert atmosphere 3: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 5 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 4 steps 1.1: sulfuric acid; potassium iodate; potassium iodide / ethanol / 2 h / 75 °C 2.1: n-butyllithium / toluene; diethyl ether; hexane / 1 h / -45 - -5 °C / Inert atmosphere 2.2: 2 h / -45 °C / Inert atmosphere 3.1: hydrogenchloride / water; toluene; diethyl ether; hexane / 20 °C / Inert atmosphere 4.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / water; toluene / 7 h / 80 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: N-Bromosuccinimide / N,N-dimethyl-formamide / 12 h / 20 °C 2: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 12 h / Reflux View Scheme |