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CAS No.: | 13815-16-2 |
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Name: | Triaminomonochloro platinum (II) chloride |
Article Data: | 34 |
Molecular Structure: | |
Formula: | ClH6N3Pt-3 |
Molecular Weight: | 317.078 |
Synonyms: | 2,3,4-triaminopyridine;triaminopyridine;Pyridin-2,3,4-triyltriamin;2,3,4-pyridinetriamine;pyridine-2,3,4-triyltriamine; |
Density: | g/cm3 |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
PSA: | 78.06000 |
LogP: | 1.01610 |
transplatin
triamminechloroplatinum(II) chloride
Conditions | Yield |
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With hydrogenchloride; ammonium hydroxide; silver nitrate In water; N,N-dimethyl-formamide byproducts: AgCl; Pt-complex reacted with a soln. of AgNO3 in DMF overnight; filtered; aq. NH4OH added; evapd. to dryness; dissolved in aq. HCl; concentrated; ethanol added; cooled to -20°C; pptd.; recrystd. from 0.1 M HCl/ethanol; elem. anal.; | 47% |
Conditions | Yield |
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With ammonia In water effect of NH3 forms a small amount of (Pt(NH3)3Cl)Cl and a great amount of (Pt(NH3)4)Cl2;; | |
With NH3 In water effect of NH3 forms a small amount of (Pt(NH3)3Cl)Cl and a great amount of (Pt(NH3)4)Cl2;; | |
With NH3 In water dropwise addn. of NH3-soln. to a cis-(Pt(NH3)2Cl2)-soln. heated at 95-98°C;; |
cisplatin
triamminechloroplatinum(II) chloride
Conditions | Yield |
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With potassium cyanate In water byproducts: NH3; effect of KCNO;; | |
With water In not given formation at heating of cis-(Pt(NH3)2Cl2) in presence of H2O at 100°C under a pressure of 4250 atm;; | <1 |
With H2O In not given formation at heating of cis-(Pt(NH3)2Cl2) in presence of H2O at 100°C under a pressure of 4250 atm;; | <1 |
With KCNO In water byproducts: NH3; effect of KCNO;; |
triamminechloroplatinum(II) chloride
Conditions | Yield |
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In not given formation at reaction of (Pt(NH3)3Cl)2(PtCl4) with (Pt(NH3)4)Cl2;; recrystallization in dild. alcohol;; | |
In not given formation at reaction of (Pt(NH3)3Cl)2(PtCl4) with (Pt(NH3)4)Cl2;; recrystallization in dild. alcohol;; |
Conditions | Yield |
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With hydrogenchloride; potassium cyanate; potassium tetrachloroplatinate In water byproducts: [Pt(NH3)4][PtCl4], [Pt(NH3)3Cl]2[PtCl4]; cis-(Pt(NH3)2Cl2) and KNCO boiled in water for 1 min, concd. HCl added,unreacted Pt-complex filtered off, K2PtCl4 added, (PtNH3)4)(PtCl4) and (Pt(NH3)3Cl)2(PtCl4) sepd., the filtrate yielded a solid, dissolved in aq. HCl, treated with (Pt(NH3)4)Cl2; the product was obtained by leaving the soln. over P2O5 in a dessicator; |
hydrogenchloride
triamminechloroplatinum(II) chloride
Conditions | Yield |
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In hydrogenchloride formation at effect of HCl-soln. on (Pt(NH3)4)Cl2;; | |
In hydrogenchloride formation at effect of HCl-soln. on (Pt(NH3)4)Cl2;; |
triamminechloroplatinum(II) chloride
Conditions | Yield |
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In hydrogenchloride formation at boiling of (Pt(NH3)4)Cl2*H2O with 8% excess (Pt(NH3)3Cl)2(PtCl4) and H2O containing HCl for 3 min; cooling down; concn. in vac.; filtration; evaporation in vac. over H2SO4 and storing over sodium lime;; |
cisplatin
triamminechloroplatinum(II) chloride
Conditions | Yield |
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With ammonia In ammonia | |
With NH3 In ammonia aq. ammonia=NH3; | |
In ammonia |
Conditions | Yield |
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In not given formation at addn. of NH3 to cis-(Pt(NH3)2Cl2);; | |
In not given formation at addn. of NH3 to cis-(Pt(NH3)2Cl2);; | |
In ammonia aq. ammonia=NH3; formation from cis-(Pt(NH3)2Cl2) and NH3-soln.;; not isolated;; |
transplatin
triamminechloroplatinum(II) chloride
Conditions | Yield |
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With ammonia In ammonia effect of NH3;; | |
With NH3 In ammonia aq. ammonia=NH3; effect of NH3;; |