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CAS No.: | 13894-28-5 |
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Name: | ethyl (E)-3-diethylaminoprop-2-enoate |
Article Data: | 12 |
Molecular Structure: | |
Formula: | C9H17 N O2 |
Molecular Weight: | 171.239 |
Synonyms: | 2-Propenoicacid, 3-(diethylamino)-, ethyl ester, (E)-; Acrylic acid, 3-(diethylamino)-,ethyl ester, (E)- (8CI); Ethyl (E)-3-(N,N-diethylamino)propenoate; Ethyl(E)-3-(diethylamino)acrylate |
Density: | 0.943g/cm3 |
Boiling Point: | 227.3°Cat760mmHg |
Flash Point: | 80.5°C |
PSA: | 29.54000 |
LogP: | 1.40500 |
ethyl 3-(diethylamino)-3-oxopropanoate
ethyl 3-(diethylamino)acrylate
Conditions | Yield |
---|---|
With bis(triphenylphosphine)carbonyliridium(I) chloride; 1,1,3,3-Tetramethyldisiloxane In toluene at 20℃; for 1h; Inert atmosphere; chemoselective reaction; | 92% |
Conditions | Yield |
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With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; (E)-1-bromo-2-iodoethylene In tetrahydrofuran at 23℃; for 12h; | 92% |
With benzene | |
In ethanol | |
In ethanol | 29.83 g (87 %) |
N,N-diethyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-amine
propynoic acid ethyl ester
ethyl 3-(diethylamino)acrylate
Conditions | Yield |
---|---|
With sodium t-butanolate; tricyclohexylphosphine In methanol at 70℃; for 17h; Inert atmosphere; Schlenk technique; | 93% |
Conditions | Yield |
---|---|
With zinc dibromide In acetonitrile at 50 - 60℃; for 13h; | 53% |
ethyl 3-(trimethylsilyl)propynoate
diethylamine
ethyl 3-(diethylamino)acrylate
Conditions | Yield |
---|---|
In diethyl ether for 4h; | 34% |
(E)-1,1,1-Trichloro-4-(N,N-diethylamino)but-3-en-2-one
sodium ethanolate
ethyl 3-(diethylamino)acrylate
Conditions | Yield |
---|---|
In ethanol | 95% |
In ethanol Product distribution; | 95% |
C9H17NO2
ethyl 3-(diethylamino)acrylate
Conditions | Yield |
---|---|
at 130 - 175℃; |
diethylamine
propynoic acid ethyl ester
benzene
ethyl 3-(diethylamino)acrylate
Conditions | Yield |
---|---|
reagiert analog mit Anilin und Piperidin; |
ethyl 3-(diethylamino)acrylate
(Z)-1-bromo-1-heptene
ethyl 2,4-decadienoate
Conditions | Yield |
---|---|
(i) Li, Et2O, (ii) /BRN= 2083336/; Multistep reaction; |
ethyl 3-(diethylamino)acrylate
ethyl α(E)-[(diethylamino)methylene]-3-ethyl-2,4,5-trifluoro-β-oxo-benzenepropanoate
Conditions | Yield |
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With triethylamine In toluene at 90℃; for 5h; | 750 mg |