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13894-28-5

Basic Information
CAS No.: 13894-28-5
Name: ethyl (E)-3-diethylaminoprop-2-enoate
Article Data: 12
Molecular Structure:
Molecular Structure of 13894-28-5 (ethyl (E)-3-diethylaminoprop-2-enoate)
Formula: C9H17 N O2
Molecular Weight: 171.239
Synonyms: 2-Propenoicacid, 3-(diethylamino)-, ethyl ester, (E)-; Acrylic acid, 3-(diethylamino)-,ethyl ester, (E)- (8CI); Ethyl (E)-3-(N,N-diethylamino)propenoate; Ethyl(E)-3-(diethylamino)acrylate
Density: 0.943g/cm3
Boiling Point: 227.3°Cat760mmHg
Flash Point: 80.5°C
PSA: 29.54000
LogP: 1.40500
Synthetic route
33567-70-3

ethyl 3-(diethylamino)-3-oxopropanoate

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
With bis(triphenylphosphine)carbonyliridium(I) chloride; 1,1,3,3-Tetramethyldisiloxane In toluene at 20℃; for 1h; Inert atmosphere; chemoselective reaction;92%
109-89-7

diethylamine

623-47-2

propynoic acid ethyl ester

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; (E)-1-bromo-2-iodoethylene In tetrahydrofuran at 23℃; for 12h;92%
With benzene
In ethanol
In ethanol29.83 g (87 %)
791785-35-8

N,N-diethyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-amine

623-47-2

propynoic acid ethyl ester

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
With sodium t-butanolate; tricyclohexylphosphine In methanol at 70℃; for 17h; Inert atmosphere; Schlenk technique;93%
121-44-8

triethylamine

623-47-2

propynoic acid ethyl ester

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
With zinc dibromide In acetonitrile at 50 - 60℃; for 13h;53%
16205-84-8

ethyl 3-(trimethylsilyl)propynoate

109-89-7

diethylamine

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
In diethyl ether for 4h;34%
24960-56-3

(E)-1,1,1-Trichloro-4-(N,N-diethylamino)but-3-en-2-one

141-52-6

sodium ethanolate

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
In ethanol95%
In ethanol Product distribution;95%
54299-82-0

C9H17NO2

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
at 130 - 175℃;
109-89-7

diethylamine

623-47-2

propynoic acid ethyl ester

71-43-2

benzene

13894-28-5

ethyl 3-(diethylamino)acrylate

Conditions
ConditionsYield
reagiert analog mit Anilin und Piperidin;
13894-28-5

ethyl 3-(diethylamino)acrylate

39924-57-7

(Z)-1-bromo-1-heptene

Conditions
ConditionsYield
(i) Li, Et2O, (ii) /BRN= 2083336/; Multistep reaction;

3-ethyl-2,4,5-trifluoro-benzoyl chloride

13894-28-5

ethyl 3-(diethylamino)acrylate

925457-03-0

ethyl α(E)-[(diethylamino)methylene]-3-ethyl-2,4,5-trifluoro-β-oxo-benzenepropanoate

Conditions
ConditionsYield
With triethylamine In toluene at 90℃; for 5h;750 mg
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