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| CAS No.: | 15805-73-9 |
|---|---|
| Name: | Vinyl Carbamate |
| Article Data: | 5 |
| Molecular Structure: | |
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|
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| Formula: | C3H5 N O2 |
| Molecular Weight: | 87.09 |
| Synonyms: | Carbamicacid, vinyl ester (7CI,8CI); Ethenyl carbamate; NSC 133266; Vinyl carbamate |
| Density: | 1.084g/cm3 |
| Melting Point: | 52-54°C |
| Boiling Point: | 186.5°Cat760mmHg |
| Flash Point: | 103.8°C |
| Safety: | Poison by intraperitoneal route. Questionable carcinogen with experimental neoplastigenic data. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS and CARBAMATES. |
| PSA: | 52.32000 |
| LogP: | 0.92550 |
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Chemistry
Vinyl carbamate with CAS register number of 15805-73-9 is also called for Carbamic acid, ethenyl ester ; Ethenyl Ester Carbamic Acid ; NSC 133266 ; Vinyl Ester Carbamic Acid ; benzyl N-vinylcarbamate ; CCRIS 6542 ; CHEBI:27292 ; Vinyl carbamate (transgenic LEP) ,and so on. Vinyl carbamate (CAS No.15805-73-9) is usually white solid.
IUPAC Name: Ethenyl carbamate
CAS: 15805-73-9
Molecular Formula: C3H5NO2
Molecular Weight: 87.0773
Molecular structure:
Melting point: 52-54°C
ACD/LogP: -0.01
ACD/LogD (pH 5.5): -0.01
ACD/LogD (pH 7.4): -0.01
ACD/BCF (pH 5.5): 1
ACD/BCF (pH 7.4): 1
ACD/KOC (pH 5.5): 23.41
ACD/KOC (pH 7.4): 23.41
H bond acceptors: 3
H bond donors: 2
Freely Rotating Bonds: 2
Index of Refraction: 1.435
Molar Refractivity: 20.98 cm3
Molar Volume: 80.3 cm3
Polarizability: 8.31×10-24cm3
Surface Tension: 34.2 dyne/cm
Density: 1.084 g/cm3
Flash Point: 103.8 °C
Enthalpy of Vaporization: 42.27 kJ/mol
Boiling Point: 186.5 °C at 760 mmHg
Vapour Pressure: 0.662 mmHg at 25°C
Uses
1. Vinyl carbamate (CAS No.15805-73-9) is commonly used as a potent promutagen.
2. Vinyl carbamate (CAS No.15805-73-9) is also mutagenic to Salmonella typhimurium TA 1535 and TA 100 in the presence of reduced nicotinamide adenine dinucleotide phosphate-fortified rat or mouse liver mitochondrial supernatant fractions.
Toxicity Data With Reference
| 1. | sce-hmn:lym 10 mmol/L | MUREAV Mutation Research. 89 (1981),75. | ||
| 2. | sce-rat-ipr 25 mg/kg | MUREAV Mutation Research. 126 (1984),159. | ||
| 3. | ipr-mus LDLo:125 mg/kg | CNREA8 Cancer Research. 38 (1978),3793. |
Safety Profile
Poison by intraperitoneal route. Questionable carcinogen with experimental neoplastigenic data. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS and CARBAMATES.
Specification
Removal in wastewater treatment of Vinyl carbamate (CAS No.15805-73-9) can be stated as follws:
Total removal:1.86 percent
Total biodegradation:0.09 percent
Total sludge adsorption:1.76 percent
Total to Air:0.01 percent
(using 10000 hr Bio P,A,S)