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CAS No.: | 186259-63-2 |
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Name: | 2,7-Dibromo-9,9-diphenylfluororene |
Article Data: | 13 |
Molecular Structure: | |
Formula: | C25H16Br2 |
Molecular Weight: | 476.21 |
Synonyms: | 2,7-Dibromo-9,9-diphenyl-9H-fluorene; |
EINECS: | 1533716-785-6 |
Density: | 1.548 g/cm3 |
Melting Point: | 279-281 °C |
Boiling Point: | 520.3 °C at 760 mmHg |
Flash Point: | 311.1 °C |
PSA: | 0.00000 |
LogP: | 7.57470 |
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide for 5h; Sonication; | 98% |
2,7-dibromo-(9-phenyl-9H-fluoren-9-ol)
benzene
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid at 80℃; for 6h; Reflux; | 93% |
With trifluorormethanesulfonic acid at 80℃; for 6h; Friedel-Crafts reaction; | 88% |
With trifluorormethanesulfonic acid at 50 - 80℃; for 6h; Inert atmosphere; Schlenk technique; | 70% |
9,9-diphenylfluorene
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
With bromine; acetic acid In chloroform for 1h; Inert atmosphere; Reflux; | 90% |
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid at 100℃; for 1h; | 89% |
2,7-dibromofluorene-9-one
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: diethyl ether / 3 h / Heating 2: conc. H2SO4 / 3 h View Scheme | |
Multi-step reaction with 2 steps 1: 90 percent / diethyl ether / Heating 2: 88 percent / CF3SO3H / 6 h / 80 °C View Scheme | |
Multi-step reaction with 2 steps 1.1: magnesium / diethyl ether / 4 h / Reflux 1.2: 12 h / Reflux 2.1: trifluorormethanesulfonic acid / Heating View Scheme |
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: diethyl ether / 3 h / Heating 2: conc. H2SO4 / 3 h View Scheme |
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 94 percent / tetrahydrofuran; hexane / 17 h / -78 - 20 °C 2: 89 percent / H2SO4; AcOH / 1 h / 100 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 94 percent / tetrahydrofuran; hexane / 17 h / -78 - 20 °C 2: 89 percent / H2SO4; AcOH / 1 h / 100 °C View Scheme |
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 90 percent / diethyl ether / Heating 2: 88 percent / CF3SO3H / 6 h / 80 °C View Scheme |
bromobenzene
2,7-dibromo-9,9-diphenyl-9H-fluorene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: magnesium / diethyl ether / 4 h / Reflux 1.2: 12 h / Reflux 2.1: trifluorormethanesulfonic acid / Heating View Scheme |
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The 2,7-Dibromo-9,9-diphenylfluororene is an organic compound with the formula C25H16Br2. The systematic name of this chemical is 2,7-dibromo-9,9-diphenyl-9H-fluorene. With the CAS registry number 186259-63-2, it is also named as 9H-fluorene, 2,7-dibromo-9,9-diphenyl-. The product's categories are Fluorene Derivatives; Electronic Chemicals.
The other characteristics of this product can be summarized as: (1)ACD/LogP: 7.80; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 7.8; (4)ACD/LogD (pH 7.4): 7.8; (5)ACD/BCF (pH 5.5): 501784.44; (6)ACD/BCF (pH 7.4): 501784.44; (7)ACD/KOC (pH 5.5): 418795.16; (8)ACD/KOC (pH 7.4): 418795.16; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: Å2; (13)Index of Refraction: 1.693; (14)Molar Refractivity: 117.96 cm3; (15)Molar Volume: 307.5 cm3; (16)Polarizability: 46.76×10-24 cm3; (17)Surface Tension: 55.3 dyne/cm; (18)Density: 1.548 g/cm3; (19)Flash Point: 311.1 °C; (20)Enthalpy of Vaporization: 76.34 kJ/mol; (21)Boiling Point: 520.3 °C at 760 mmHg; (22)Vapour Pressure: 2.08E-10 mmHg at 25°C.
People can use the following data to convert to the molecule structure.
1. SMILES:Brc3ccc4c1ccc(Br)cc1C(c2ccccc2)(c4c3)c5ccccc5
2. InChI:InChI=1/C25H16Br2/c26-19-11-13-21-22-14-12-20(27)16-24(22)25(23(21)15-19,17-7-3-1-4-8-17)18-9-5-2-6-10-18/h1-16H
3. InChIKey:AJYDOCCGNIBJBY-UHFFFAOYAD
4. Std. InChI:InChI=1S/C25H16Br2/c26-19-11-13-21-22-14-12-20(27)16-24(22)25(23(21)15-19,17-7-3-1-4-8-17)18-9-5-2-6-10-18/h1-16H
5. Std. InChIKey:AJYDOCCGNIBJBY-UHFFFAOYSA-N